Non-Heme Mononitrosyldiiron Complexes: Importance of Iron Oxidation State in Controlling the Nature of the Nitrosylated Products

Abstract

Mononitrosyldiiron complexes having either an [Fe<sup>II</sup>·{FeNO}<sup>7</sup>] or an [Fe<sup>III</sup>·{FeNO}<sup>7</sup>] core formulation have been synthesized by methods that rely on redox-state-induced differentiation of the diiron starting materials in an otherwise symmetrical dinucleating ligand environment. The synthesis, X-ray structures, Mössbauer spectroscopy, cyclic voltammetry, and dioxygen reactivity of [Fe<sup>III</sup>·{FeNO}<sup>7</sup>] are described

    Similar works

    Full text

    thumbnail-image

    Available Versions