Facile and Highly Efficient Strategy for Synthesis of Functional Polyesters via Tetramethyl Guanidine Promoted Polyesterification at Room Temperature

Abstract

A facile and highly efficient strategy for the synthesis of functional polyesters from 10-undecenoic acid, which is abundantly available and derived from ricin oil, has been successfully achieved using 1,1,3,3-tetramethyl guanidine (TMG) as a promoter at room temperature. The experimental results indicate that high molecular weight polyesters have been obtained and a variety of functional groups, such as alkenyl, alkynyl, nitro, epoxy, hydroxyl, and bromoisobutyrate, can be incorporated as pendant groups. The structures of the obtained polymers were demonstrated by ¹H and ¹³C NMR spectroscopy and their thermal properties were studied by DSC and TGA