Formation of Carbocycles via a 1,4-Rh Shift Triggered by a Rhodium-Catalyzed Addition of Terminal Alkynes to 3,3-Diarylcyclopropenes

Abstract

The catalytic addition of terminal alkynes to 3,3-diarylcyclopropenes in the presence of a Rh­(I)/binap complex proceeded to give the cycloaddition products in good yields, where a 1,4-Rh shift is involved as a key step

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