Investigating the Dearomative Rearrangement of Biaryl Phosphine-Ligated Pd(II) Complexes

Abstract

A series of monoligated L·Pd<sup>II</sup>(Ar)­X complexes (L = dialkyl biaryl phosphine) have been prepared and studied in an effort to better understand an unusual dearomative rearrangement previously documented in these systems. Experimental and theoretical evidence suggest a concerted process involving the unprecedented Pd<sup>II</sup>-mediated insertion of an aryl group into an unactivated arene

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