Tertiary Amine-Triggered Cascade S<sub>N</sub>2/Cycloaddition: An Efficient Construction of Complex Azaheterocycles under Mild Conditions


In this paper, an amine-triggered cascade S<sub>N</sub>2/cycloaddtion sequence between 2-(acetoxymethyl)buta-2,3-dienoate <b>1</b> and various π-system functionalized tosylamides <b>3</b> has been reported, which provides a facile method for stereoselective construction of structurally diverse azaheterocycles

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