Access to C(sp<sup>3</sup>)–C(sp<sup>2</sup>) and C(sp<sup>2</sup>)–C(sp<sup>2</sup>) Bond Formation via Sequential Intermolecular Carbopalladation of Multiple Carbon–Carbon Bonds

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    Abstract

    A synthetic strategy of 4-benzyl-substituted 1,3-butadiene derivatives through Pd-catalyzed three-component coupling reaction of benzyl chlorides, alkynes, and monosubstituted alkenes is described. This tandem coupling reaction forms a C­(sp<sup>3</sup>)–C­(sp<sup>2</sup>) bond and a C­(sp<sup>2</sup>)–C­(sp<sup>2</sup>) bond sequentially in a single-step operation

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      Last time updated on 12/02/2018