Chiral Cu(salen)-Based Metal–Organic Framework for Heterogeneously
Catalyzed Aziridination and Amination of Olefins
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Abstract
A homochiral 3D porous
metal–organic framework was assembled from a chiral dicarboxylic
acid-functionalized Cu(salen)-based catalyst and could serve as an
efficient heterogeneous catalyst for aziridination and allylic amination
of olefins. Besides easy separation and reuse of the catalyst, the
chiral framework confinement could impart substrate size selectivity,
enhance catalyst activity, and induce product enantioselectivity