Directional Scattering and Sensing with Bimetallic Fanocubes: A Complex Fano-Resonant Plasmonic Nanostructure

Abstract

Concentric nanostructures provide a unique architecture to manipulate light by modification of their internal geometry with minimal changes to their overall size. In this work, we have theoretically examined, using finite difference time domain simulations, the plasmonic properties of a concentric cubic nanostructure consisting of a silver (Ag) core, silica (SiO<sub>2</sub>) interlayer, and gold (Au) shell. These “bimetallic fanocubes” display two separate geometry dependent Fano resonances in the visible and in the near-infrared. We employed a plasmon hybridization model to understand the origin of the spectral features and observe distinct hybridized modes contributed by the edges and corners, which is unique to the cubic geometry. Specifically, we note that the “nonbonding” mode that is essentially dark and not observable in spherical concentric nanostructures is enhanced in the bimetallic fanocubes. We show the far-field properties, and Fano resonances of the fanocubes can be tuned by altering the thickness of the silica layer, the thickness of the Au shell, and by breaking symmetry. Further, we have examined the refractive index sensing and directional scattering abilities of the fanocubes to ultimately enable their use in a range of applications, harnessing their absorption and scattering properties

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