Rhodium-Catalyzed Alkenylation of C–H Bonds in Aromatic Amides with Alkynes


The rhodium-catalyzed alkenylation of C–H bonds of aromatic amides with alkynes is reported. A variety of functional groups, including OMe, OAc, Br, Cl, and even NO<sub>2</sub>, are applicable to this reaction to give the corresponding hydroarylation products. The presence of an 8-aminoquinoline group as the directing group is crucial for the success of the reaction

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