Giant photovoltaic effect due to bulk photovoltaic effect observed in
multiferroic BiFeO3 thin films has triggered a renewed interest on
photoferroelectric materials for photovoltaic applications. Tremendous advance
has been done to improve power conversion efficiency (up to up to 8.1%) in
photoferroelectrics via absorption increase using narrow bandgap
ferroelectrics. Other strategies, as it is the more efficient use of
ferroelectric internal electric field, are ongoing. Moreover, as a by-product,
several progress have been also achieved on photostriction that is the
photo-induced deformation phenomenon. Here, we review ongoing and promising
routes to improve ferroelectrics photoresponse