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Local electronic properties of the graphene-protected giant Rashba-split BiAg2_2 surface

Abstract

We report the preparation of the interface between graphene and the strong Rashba-split BiAg2_2 surface alloy and investigatigation of its structure as well as the electronic properties by means of scanning tunneling microscopy/spectroscopy and density functional theory calculations. Upon evaluation of the quasiparticle interference patterns the unpertrubated linear dispersion for the π\pi band of nn-doped graphene is observed. Our results also reveal the intact nature of the giant Rashba-split surface states of the BiAg2_2 alloy, which demonstrate only a moderate downward energy shift upon the presence of graphene. This effect is explained in the framework of density functional theory by an inward relaxation of the Bi atoms at the interface and subsequent delocalisation of the wave function of the surface states. Our findings demonstrate a realistic pathway to prepare a graphene protected giant Rashba-split BiAg2_2 for possible spintronic applications.Comment: text and figures; submitted on 30.12.201

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