Polyvinyl acetate (PVAc) nanofibers were prepared by technology of electrospinning with help of multi-jets electrospinning machine from acetic acid/water solvent system. The stability of the process was tested in a broad concentration region from 5 to 40 wt. % of PVAc. The main attention was carried out to study the effect of polyvinyl acetate solution concentration/viscosity onto mean diameter of prepared nanofibers. It was found that increased solution viscosity leads to increase of fibers diameters from appox. 60 nm at viscosity similar to 0.04 Pa.s to appox. 1000 nm at viscosity similar to 6-7 Pa.s. The PVAc nanofibres can be considered as a potential precursor for preparation of inorganic fibrous nanoparticles. Their dimensions can be effectively controlled by PVAc nanofibers diameter by easy diameter - concentration/viscosity optimalization

Kimmer, Dušan

Pavlínek, Vladimír

Petráš, David

Slobodian, Petr

Sáha, Petr

Institutional repository of Tomas Bata University Library

The Effect of PVAc Solution Viscosity on Diameter of PVAc Nanofibres Prepared by Technology of ElectrospinningDavid Petrasa,b, Petr Slobodiana, Vladimír Pavlíneka, Petr Sáhaa and       Dušan Kimmerb              aCentre of Polymer Systems, Polymer Centre, Tomas Bata University in Zlin,  nam. T. G. Masaryka 5555, 760 01 Zlin, Czech Republic bSPUR a.s., Tr. Tomase Bati 299, 763 02 Zlín, Czech Republic Abstract.  Polyvinyl acetate (PVAc) nanofibers were prepared by technology of electrospinning with help of multi-jets electrospinning machine from acetic acid/water solvent system. The stability of the process was tested in a broad concentration region from 5 to 40 wt. % of PVAc. The main attention was carried out to study the effect of polyvinyl acetate solution concentration/viscosity onto mean diameter of prepared nanofibers. It was found that increased solution viscosity leads to increase of fibers diameters from appox. 60 nm at viscosity ~ 0.04 Pa.s to appox. 1000 nm at viscosity ~ 6-7 Pa.s. The PVAc nanofibres can be considered as a potential precursor for preparation of inorganic fibrous nanoparticles. Their dimensions can be effectively controlled by PVAc nanofibers diameter by easy diameter - concentration/viscosity optimalization.  Keywords:  Polyvinyl acetate, PVAc, Nanofibers, Nanofiber layer, Electrospinning, Acetic acid, Water. PACS: 83.85.Jn, 81.07.-b, 81.16.-c, 83.60.-a, 83.80.Rs, 61.46.-w, 62.23.-c    INTRODUCTION Polyvinyl acetate (PVAc) is often used as a carrier polymer for preparation of inorganic nanofibers. Such inorganic nanofibers are not prepared directly, but through organic nanofiber precursor. The precursor nanofibers are usually fabricated by technology of electrospinning from PVAc solution together with appropriate well thermally decomposable metal salt. This precursor is then calcined when inorganic nanofiber or nanowhiskers are formed [1, 2]. Nanomaterials made of pure metals or their oxides are prepared according condition of calcination. This new inorganic materials are promising for application in area of semiconductors [3, 4].   The technology of electrospinning is one of the most used methods to prepare        ultra-thin fibers [5-9]. PVAc solutions are usually used for their production. But commonly used solvents like dimethylformamide, ketones or alcohols [1, 2, 5] are not Novel Trends in Rheology IVAIP Conf. Proc. 1375, 312-319 (2011); doi: 10.1063/1.3604491©   2011 American Institute of Physics 978-0-7354-0935-4/$30.00312fully environmentally acceptable because of their toxicity. Another technological disadvantage is in their flammability. The solvent system based on the mixture of acetic acid and water can significantly eliminate these problems. Finally, the reduction of the amount of acetic acid in favour of water is also advantageous form economical aspects. The structure of the prepared nanofiber precursors (polymer and metal salts) always affects the parameters of the resulting inorganic nanofibers [10]. The PVAc nanofibers diameter seems to be a basic parameter which would be controlled from this point of view. It is known that the fiber diameter is influenced by numerous parameters during electrospinning. But the basic parameter is polymer solution concentration. More concentrated solutions have higher solution viscosity, the increase in viscosity leads to thicker fibers [6, 11, 12]. The aim of this work is to test new solvent system for electrospinning of PVAc solutions based on the mixture of acetic acid with water. This system is non-toxic,        non-flammable and low-cost. Further, the broad range of concentration/viscosities is tested to find when nanofibers are formed by technology of electrospinning. Finally, the analysis of effect of solution viscosity onto nanofibers diamether is performed.  EXPERIMENTAL AND RESULTS Materials: PVAc (Mcgean, Polyvinylacetate beads B-15, Mw 90,000 g.mol-1), acetic acid (Penta Chemikalie, Czech republic, p.a.) and demineralized water (electrical conductivity 0.40 μS/cm).  Process: Three different PVAc concentrations series were prepared, one in pure acetic acid (AA) and two in mixture of acetic acid with water (AA:H2O ) in concentration  ratios 3 : 1 and 1 : 1 (v/v) from 5 to 40 wt. % of dissolved PVAc. There was attempt to prepare also solutions in volume ratio 1:3 but PVAc does not dissolve. Concentration step was      1 wt. % for concentration range from 5 to 10 wt. % and 2.5 wt. % from 10 to 40 wt. %. Homogeneous and clear solutions were prepared by mechanical stirring at 160 rpm for 4h at room temperature (22°C). Non-woven layers of PVAc nanofibers were prepared by technology of electrospinning from solutions using laboratory multi-jet apparatus      (SPUR a.s., Czech republic), see schematic illustration, Figure 1. The main processing parameters were: solution flow rate 0.4 ml/min, high voltage electrospinning electrode (multi-jest head) +80 kV DC, electrode distance 180 mm, processing                temperature: 20 ± 2°C and processing relative humidity 30.0 ± 2.5%. Aluminum foil (thickness: 0.5 mm, dimension: 300 x 300 mm) was used as collecting substrate. The duration of continuous process was about 120 s. Analyses: The structure of fibers was observed by a scanning electron microscope (SEM) Vega LMU made by Tescan s.r.o., Czech Republic. The network was deposited on the carbon targets and covered with a thin Au/Pd layer. For the observations the regime of 313secondary electrons was chosen. The fiber diameter was determined by analyzing of SEM images, n~100. Rheological properties of all solutions were determined under controlled shear rate mode using rotational viscometer (Bohlin Gemini, Malvern Instruments, UK) in concentric cylinder geometry in the shear rate range 0.6 – 60 s-1. Rotating inner cylinder of 14 mm diameter and stationary outer cylinder were separated by 0.7 mm gap. All experiments were performed at temperature of 25°C. Sample solutions showed Newtonian behaviour up to concentration of 32.5% above which pseudoplastic character was observed. Solutions viscosity at 5 s-1 (safely in Newtonian region) was selected for correlation with diameter of electrospun fibers.   FIGURE 1.  Schematic illustration of multi-jet electrospinning apparatus.  The schematic illustration of used electrospinning apparatus is presented in Figure 1. It is based on multi-jet principle when polymer solution is pumped into spinning head with parallel jets. The mass transfer from jet’s tips to collector is caused by application of high voltage field. The character of product can by from nanobeads (electro-spraying) or submicron fibers (electro-spinning) to formation of polymer conglomerates. The deposited material is solidified from the state of solution to solid state by solvent evaporation which should mainly occur during spinning process.  The effects of solvent system and PVAc concentration onto electrospinning process are summarized in Tab.1. According that the process ran or not and the structure of the product differ from nano-beads and nano-fibers to production of PVAc conglomerates.    314TABLE 1. Characterization of electrospinning process for different composition of solvent system,           acetic acid with water (AA:H2O ) and different concentration of dissolved PVAc. Solvent system PVAc wt. Concentration  [ wt. %] Process characterization AA 5 - 40 without process, no mass transfer AA:H2O - 3:1 5 – 7 electro-spraying, stable mass transfer, PVAc beds with minimum of fibers 8 – 32.5 electro-spinning, stable mass transfer, PVAc fiber creation of submicron size 32.5 - 40 unstable or no mass transfer, unstable PVAc fiber formation of micron size AA:H2O - 1:1 5 – 8 electro-spraying, stable mass transfer, PVAc beds with minimum of fibers 9 – 30 electro-spinning, stable mass transfer, PVAc fiber creation of submicron size 32.5 - 40 unstable or no mass transfer, unstable PVAc fiber formation of micron size AA:H2O - 1:3  PVAc not solved  The influence of solution concentartion onto produced fibers diamether is demonstrated by SEM analyses presented in Figure 2 and Figure 3. It represents examples of prepared PVAc non-woven mats for different PVAc concentrations and solvent system AA:H2O (3:1). It is clearly visible that the fibers diamether increase with solution concentration. Both concentration series based on mixture of AA:H2O (3:1 and 1:1) poses good    process-ability by electrospinning process. The fibers are created in very broad range of PVAc concentrations from approx. 8-9 wt. % to 30 wt. % of PVAc. On other hand electro-spraying below its lower limit or unstable process leading to PVAc micron size fiber and PVAc conglomerates above 30 wt. % of PVAc were observed.   FIGURE 2.  SEM images (at 3000x) of PVAc non-woven mats prepared by technology of electrospinning from mixture AA : H2O – 3:1 (v/v) with a) 10 wt. % of  PVAc – fiber main diameter 89 nm, b) 20 wt. % of  PVAc – fiber main diameter 401 nm, c) 30 wt. % of  PVAc – fiber main diameter 830 nm. 315 FIGURE 3.  SEM images (at 3000x) of  transition between electro-spraying and electro-spinning in solvent system AA : H2O – 3:1 (v/v): a) 5 wt. % of  PVAc, b) 7 wt. % of  PVAc c) 9 wt. % of  PVAc and d) PVAc micron size fiber and PVAc conglomerates for 32.5 wt. % of  PVAc. There were found significant differences in fibers diameters in the used concentration range. The fiber diameters differ by more than one order of magnitude. Table 2 presents an interval of fiber diameter between lower and upper PVAc concentrations.  TABLE 2. The main fiber diameter and viscosity of solutions. solution Fiber diameter (nm) Viscosity (Pa.s) AA:H2O (3:1), 9 wt. % PVAC 67 ± 10 0.066 AA:H2O (3:1), 32,5 wt. % PVAC 1171 ± 40 7.720 AA:H2O (1:1), 9 wt. % PVAC 62 ±10 0.039 AA:H2O (1:1), 32,5 wt. % PVAC 950 ± 32 6.655  Next Figure 4 presents the dependence of viscosity on the concentration of PVAc solutions measured for both concentration series. It demonstrates that viscosity increase exponentially with solutions concentration. The dependences for both concentration series are nearly identical. The similar exponential character was found for the dependence of fiber mean diameter on concentration also presented in Figure 4. Slightly thicker fibers 316are created from AA:H2O – 3 : 1 system. This fact is reflected in slightly lower viscosity of this solution, especially at PVAC concentrations higher than 15 wt %.  FIGURE 4.  Dependence of mean diameter of nanofiber (D) and solutions viscosity () on PVAC concentration (c) in solvent system AA : H2O – 3:1 (v/v) and AA : H2O – 1:1 (v/v). The influence to viscosity both solutions onto fiber diameter is presented in Figure 5. It seems that the influence of viscosity on fiber diameter is gradually decreasing. Difference between the curves of both types of solutions again increases with the increase of viscosity difference.   FIGURE 5.  Dependence of fiber diameter (D) on PVAC solution viscosity () in solvent system             AA : H2O – 3:1 (v/v) and AA : H2O – 1:1 (v/v).  317These dependencies are easy to describe a power function. Dependence of fiber diameter (D) on the viscosity () of these solutions are follows: solution AA : H2O (3:1)  D(nm) = 322,14 . (Pa.s)0.6714 and It for solution based on mixture AA : H2O (1:1):   D(nm) = 299.14 . (Pa.s)0.552. CONCLUSION The PVAc nanofibers with diameter from approximately 60 nm to 1000 nm were prepared by technology of electrospinning for acetic acid/water solvent system using  by multi-jet apparatus. The fibers diameter was controlled by one simple parameter such as PVAc solution concentration/viscosity when increased viscosity leads to production of thicker fibers. It was found that optimal volume range of acetic acid and water is 3 : 1 and 1 : 1 (v/v). The stable electrospinning process was found in PVAc concentration range from 8 to 30% (w/v) for volume ration 3 : 1 and PVAC concentration range from 9 to 30% (w/v) for volume ratio 1 : 1.  ACKNOWLEDGMENTS This article was created with support of Operational Programme Research and Development for Innovations co-funded by the European Regional Development Fund (ERDF) and national budget of Czech Republic within the framework of the Centre of Polymer Systems project (reg.number:  CZ.1.05/2.1.00/03.0111). Special thanks go to the SPUR a.s. (http://www.spur.cz/) for providing the multi-jet electrospinning laboratory device. This device was acquired with support of operational programme Ministry industry and trade: enterprise and innovation (Potential) co-funded by the european regional development fund and national budget of Czech republic within the framework of extension center for industrial research and development of commercial production of plastics (project number: 4.2PT02/017). REFERENCES  1. I. D. Kim, A. Rothschild, B. H. Lee, D. Y. Kim, S. M. Jo, and H. L. Tuller, Nano Lett. 6, 2009–2013 (2006). 2.  N. Dharmaraj, H. C. Park, C. K. Kim, H. Y. Kim, and D. R. 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The effect of PVAc solution viscosity on diameter of PVAc nanofibres prepared by technology of electrospinning

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The effect of PVAc solution viscosity on diameter of PVAc nanofibres prepared by technology of electrospinning

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