Long-Range Periodicity in Carbon Nanotube Sidewall Functionalization

Abstract

Using the Bingel reaction as a model for side-wall functionalization of single-walled carbon nanotubes, we report the discovery of highly regular, long-distance (several nanometer) patterns and examine the conditions for the occurrence of such patterns, possibly due to long-range induced reactivity. Varying periodicities of the patterns have been observed via scanning tunneling microscopy and are attributed to nanotube geometry. Patterns are most prominent on medium heavy functionalized nanotubes and likely tied to a nucleophilic reaction mechanism