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Thermal Rearrangement of Phosphine−B(C<sub>6</sub>F<sub>5</sub>)<sub>3</sub> Adducts

Abstract

A series of tertiary and secondary phosphine−B(C6F5)3 adducts are shown to undergo facile, thermal-induced rearrangement to give zwitterionic species of the form R3P(C6F4)BF(C6F5)2 and R2PH(C6F4)BF(C6F5)2, respectively

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