Development of Binaphthyl-Based Chiral Dienes for Rhodium(I)-Catalyzed Asymmetric Arylation of <i>N</i>,<i>N</i>-Dimethylsulfamoyl-Protected Aldimines

Abstract

A variety of binaphthyl-based chiral dienes were synthesized and utilized as steering ligands for the enantioselective arylation of N,N-dimethylsulfamoyl-protected aldimines with arylboronic acids, and moderate to good yields and up to 84% ee were achieved