Fast Deswelling of Nanocomposite Polymer Hydrogels via Magnetic Field-Induced Heating for Emerging FO Desalination

Abstract

Freshwater shortage is one of the most pressing global issues. Forward osmosis (FO) desalination technology is emerging for freshwater production from saline water, which is potentially more energy-efficient than the current reverse osmosis process. However, the lack of a suitable draw solute is the major hurdle for commercial implementation of the FO desalination technology. We have previously reported that thermoresponsive hydrogels can be used as the draw agent for a FO process, and this new hydrogel-driven FO process holds promise for further development for practical application. In the present work, magnetic field-induced heating is explored for the purpose of developing a more effective way to recover water from swollen hydrogel draw agents. The composite hydrogel particles are prepared by copolymerization of sodium acrylate and N-isopropylacrylamide in the presence of magnetic nanoparticles (γ-Fe2O3, <50 nm). The results indicate that the magnetic heating is an effective and rapid method for dewatering of hydrogels by generating the heat more uniformly throughout the draw agent particles, and thus, a dense skin layer commonly formed via conventional heating from the outside of the particle is minimized. The FO dewatering performance is affected by the loading of magnetic nanoparticles and magnetic field intensity. Significantly enhanced liquid water recovery (53%) is achieved under magnetic heating, as opposed to only around 7% liquid water recovery obtained via convection heating. Our study shows that the magnetic heating is an attractive alternative stimulus for the extraction of highly desirable liquid water from the draw agent in the polymer hydrogel-driven forward osmosis process