Modern applications in quantum computation and quantum communication require
the precise characterization of quantum states and quantum channels. In
practice, this means that one has to determine the quantum capacity of a
physical system in terms of measurable quantities. Witnesses, if properly
constructed, succeed in performing this task. We derive a method that is
capable to compute witnesses for identifying deterministic evolutions and
measurement-induced collapse processes. At the same time, applying the
Choi-Jamiolkowski isomorphism, it uncovers the entanglement characteristics of
bipartite quantum states. Remarkably, a statistical mixture of unitary
evolutions is mapped onto mixtures of maximally entangled states, and classical
separable states originate from genuine quantum-state reduction maps. Based on
our treatment we are able to witness these opposing attributes at once and,
furthermore, obtain an insight into their different geometric structures. The
complementarity is further underpinned by formulating a complementary Schmidt
decomposition of a state in terms of maximally entangled states and discrete
Fourier-transformed Schmidt coefficients.Comment: close to published versio