A Metal-Polymer Interface Study using Electropolymerized Acrylonitrile on Nickel Surfaces

Abstract

Studies of the interface between mineral and organic materials have been realized for a couple formed between pure transition metal and a polar and polarizable molecule (acrylonitrile). The results presented show the effects of a local electric field on the activation processes associated with adsorption sites and the molecule, interaction mechanisms and the resulting types of chemical bond. The structural, electronic and chemical properties of a nickel-polyacrylonitrile interface are described. Molecular and energetic qualitative models for the interaction mechanisms are proposed

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