An i-packing in a graph G is a set of vertices that are pairwise distance
more than i apart. A \emph{packing colouring} of G is a partition
X={X1,X2,…,Xk} of V(G) such that each colour class Xi
is an i-packing. The minimum order k of a packing colouring is called the
packing chromatic number of G, denoted by χρ(G). In this paper we
investigate the existence of trees T for which there is only one packing
colouring using χρ(T) colours. For the case χρ(T)=3, we
completely characterise all such trees. As a by-product we obtain sets of
uniquely 3-χρ-packable trees with monotone χρ-coloring
and non-monotone χρ-coloring respectively