We present a spectro-photometric analysis of 2880 cool white dwarfs within
100 pc of the Sun and cooler than Teff = 10,000 K, with grizy Pan-STARRS
photometry and Gaia trigonometric parallaxes available. We also supplement our
data sets with near-infrared JHK photometry, when available, which is shown to
be essential for interpreting the coolest white dwarfs in our sample. We
perform a detailed analysis of each individual object using state-of-the-art
model atmospheres appropriate for each spectral type including DA, DC, DQ, DZ,
He-rich DA, and the so-called IR-faint white dwarfs. We discuss the temperature
and mass distributions of each subsample, as well as revisit the spectral
evolution of cool white dwarfs. We find little evidence in our sample for the
transformation of a significant fraction of DA stars into He-atmosphere white
dwarfs through the process of convective mixing between Teff = 10,000 K and
6500 K, although the situation changes drastically in the range Teff = 6500 -
5500 K where the fraction of He-atmosphere white dwarfs reaches 45%. However,
we also provide strong evidence that at even cooler temperatures (Teff < 5200
K), most DC white dwarfs have H atmospheres. We discuss a possible mechanism to
account for this sudden transformation from He- to H-atmosphere white dwarfs
involving the onset of crystallization and the occurrence of magnetism.
Finally, we also argue that DQ, DZ, and DC white dwarfs may form a more
homogeneous population than previously believed.Comment: Accepted for publication in MNRAS (21 pages, 20 figures