Insights into Shape Selectivity and Acidity Control
in NiO-Loaded Mesoporous SBA-15 Nanoreactors for Catalytic Conversion
of Cellulose to 5‑Hydroxymethylfurfural
Facilitated isomerization of cellulose
hydrolysis intermediate
glucose without unexpected byproducts, which is the rate-determining
step in the production of high-value-added biofuels, enables the efficient
production of 5-hydroxymethylfurfural (5-HMF) from cellulose. In this
work, considering the essential role of the acidity control and shape
selectivity of a zeolite catalyst, a NiO-loaded mesoporous NiO/poly(vinyl
pyrrolidone) (PVP)-phosphotungstic acid (HPA)@SBA-15 nanoreactor was
prepared. This SBA-15 nanoreactor with a pore size of 5.47 nm reduced
the concentration of byproducts formic acid (FA) and levulinic acid
(LA) through shape selection for intermediates. Well-defined NiO nanoparticles
(Ni-to-carrier mass ratio was 1:1) provided the NiO/PVP-HPA@SBA-15
nanoreactor a high Lewis acidity of 99.29 μmol g–1 for glucose catalytic isomerization, resulting in an increase in
total reducing sugar (TRS) yield by 5 times. Such a nanoreactor remarkably
improved the reaction efficiency of 5-HMF production from cellulose
(a 5-HMF selectivity of 95.81%) in the 1-butyl-3-methylimidazolium
chloride ([BMIM]Cl)/valerolactone (GVL) biphasic system