Abstract. Described here is a proposed experiment to use laser-assisted photorecombination of positrons from a trap-based beam and metal atoms in the gas phase to measure positron-atom binding energies. Signal rates are estimated, based in part upon experience studying resonant annihilation spectra using a trapbased positron beam. While positrons are important in many areas of science and technology including materials science, medicine and astrophysics, there are a number of open, fundamental questions regarding positron interactions with ordinary matter. One such topic is positron binding to atoms and molecules. There are accurate theoretical calculations of positron binding to atoms  The goal of this paper is the development of a method to study positron-atom bound states using laser-assisted photorecombination, which should lead to enhanced annihilation

C M Surko

G F Gribakin

J R Danielson

R E Continetti

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T h e  o p e n – a c c e s s  j o u r n a l  f o r  p h y s i c s
New Journal of Physics
Measuring positron–atom binding energies through
laser-assisted photorecombination
C M Surko1,4, J R Danielson1, G F Gribakin2 and R E Continetti3
1 Department of Physics, University of California, San Diego, La Jolla,
CA 92093, USA
2 School of Mathematics and Physics, Queen’s University Belfast,
Belfast BT7 1NN, UK
3 Department of Chemistry and Biochemistry, University of California,
San Diego, La Jolla, CA 92093 USA
E-mail: csurko@ucsd.edu
New Journal of Physics 14 (2012) 065004 (6pp)
Received 10 April 2012
Published 1 June 2012
Online at http://www.njp.org/
doi:10.1088/1367-2630/14/6/065004
Abstract. Described here is a proposed experiment to use laser-assisted
photorecombination of positrons from a trap-based beam and metal atoms in the
gas phase to measure positron–atom binding energies. Signal rates are estimated,
based in part upon experience studying resonant annihilation spectra using a trap-
based positron beam.
While positrons are important in many areas of science and technology including materials
science, medicine and astrophysics, there are a number of open, fundamental questions
regarding positron interactions with ordinary matter. One such topic is positron binding to atoms
and molecules. There are accurate theoretical calculations of positron binding to atoms [1].
However, the predictions of these theories have not been tested experimentally due to the
difficulty in forming positron–atom bound states in two-body collisions. In contrast, there
have been extensive experimental studies of positron binding to molecules. Positron–molecule
collisions can lead to positron capture in vibrational Feshbach resonances, and the signatures
of these resonances in the annihilation spectra have been used to measure positron–molecule
binding energies [2, 3]. By way of further contrast, calculations of such binding energies in the
positron–molecule case have proven to be much more difficult than for atoms [4, 5].
The goal of this paper is the development of a method to study positron–atom bound
states using laser-assisted photorecombination, which should lead to enhanced annihilation.
4 Author to whom any correspondence should be addressed.
New Journal of Physics 14 (2012) 065004
1367-2630/12/065004+06$33.00 © IOP Publishing Ltd and Deutsche Physikalische Gesellschaft
2
Figure 1. Schematic diagram of the experimental arrangement (top), and the
corresponding electrical potential profile along the magnetic axis (bottom).
A process similar to this has been proposed to form antihydrogen atoms from positron and
antiproton plasmas [6] and negative ions [7]. With regard to the present application, other
possible experimental approaches to measuring positron–atom binding energies are discussed
in [8–10].
The envisioned experimental arrangement is shown schematically in figure 1. Except for
the inclusion of a laser beam, it is similar to that used previously to measure positron–molecule
binding energies. Pulses of positrons with a small thermal energy spread !" (e.g. !40 meV full-
width at half-maximum (FWHM)) from a buffer-gas positron accumulator are passed through a
cell containing the test gas, in this case a ‘hot cell’ at elevated temperature to provide sufficient
atomic number density na. The variable electrical potential of the annihilation cell is used to
set the positron energy. A pulsed laser beam with tunable photon energy h̄# is introduced
collinearly with the positron beam. The laser and positron beams are arranged so as to have
maximum overlap in the region of view of a CsI detector that is used to measure single 511 keV
gamma rays from two-quantum positron–atom annihilation. The detector is gated to monitor
annihilation events only when both the positron and laser pulses are present.
The condition for a photo-enhanced signal is
h̄# = " + "b, (1)
where " is the total kinetic energy of the positrons in the gas cell, and "b is the positron–atom
binding energy. Knowing h̄# and tuning " to this resonance condition thus provides a method
for measuring "b.
Following an approach similar to that used to describe photodisintegration of the deuteron
(i.e. assuming a zero-range-potential wave function of the positron–atom bound state and
a plane-wave description of the incident positron) [11], the differential cross-section for
positron–atom recombination accompanied by the spontaneous emission of a photon of a given
polarization is
d$r
d%
= 2&3a20
"
"b"
"b + "
cos2 ', (2)
New Journal of Physics 14 (2012) 065004 (http://www.njp.org/)
3
where & # 1/137 is the fine-structure constant, a0 is the Bohr radius, ' is the angle between the
positron momentum and the photon polarization vector and d% is the element of the solid angle
into which the photon is emitted. The presence of a quasi-monochromatic light field of intensity
I will enhance the recombination cross-section d$r/d% in the solid angle d% in which photons
are present. The enhanced, total stimulated recombination cross-section is
$sr =
!
d$r
d%
"
(, (3)
where the cross-section of equation (2) has been averaged over ' (see below), and the
dimensionless enhancement factor ( is [7, 11]
( = 8)
3c2 I
#3
f (h̄# $ "b), (4)
with f (") the positron energy distribution function normalized as
#
f (") d" = 1. Equation (4)
assumes that the laser bandwidth is much smaller than the positron energy spread, which is
characterized by f (") ! 1/!". Equations (2)–(4) agree to within a numerical factor with those
developed in [7] where the theory was used to describe laser-stimulated photorecombination of
electrons with molecules to produce dipole-bound anions.
In order to estimate the expected signal level, specification of further details of the
experimental setup is required. We assume that the positron beam consists of pulses of duration
*p, containing Np positrons with velocity v, energy " and total energy spread !". They are
magnetically guided through the cell at a frequency +p. A rotating electric field in the buffer-gas
positron accumulator will be used to compress the positrons radially to a transverse radial extent
rp in the gas cell, which will be in a magnetic field of 0.08 T.
The gamma ray detector is assumed to monitor annihilation over a length LD of the
coincident laser and positron beams. The efficiency of the detector, including the collection
solid angle, is ,D. The laser pulses with total energy E per pulse are assumed to have a time
duration *l % *p.
The rate of photo-induced bound state formation per positron is
- = na$srv, (5)
where na is the atomic number density. If the positron pulses are long in spatial extent compared
with LD, i.e. LD % v*p, the number of positrons in view of the detector (and available for bound-
state formation) will be NpLD/v*p. It is assumed that all positrons in bound states annihilate in
a time of a few nanoseconds in two gamma events and hence these gamma rays are available for
detection. With these assumptions, the rate at which either of the two annihilation gamma rays
will be detected when both the laser and positron beams are present is
$S = na$sr
%
2,D Np
LD
*p
&
. (6)
This rate is maintained only during the time *l that the laser pulse is on; thus the average number
of detected counts per single laser pulse will be N̄c = S̃*l, which can be a fraction of a count per
pulse. Taking into account the positron pulse rate +p, the overall expected signal rate will be
S = 2na$sr,D NpLD+p
*l
*p
. (7)
Due to the fact that $sr & ( , and for laser pulses of fixed energy, ( & 1/*l; the signal rate S is
independent of the laser pulse duration *l.
New Journal of Physics 14 (2012) 065004 (http://www.njp.org/)
4
Table 1. Assumed parameters for measuring positron–atom binding energies by
photorecombination and monitoring subsequent, prompt annihilation.
Positrons
Pulse strength Np 1 ' 105
Pulse rate +p (Hz) 3
Pulse duration *p (µs) 1.5
Beam radius rp(mm) 1.5
Total positron energy " (eV) 0.25
Perpendicular energy spread kT (eV) 0.025
Total beam energy spread !" (eV) 0.040
Laser
Photon energy h̄# (eV) 0.35
Pulse energy E (mJ) 10
Pulse duration *l (ns) 3.0
Beam radius r (mm) 1.5
Intensity I (MW cm$2) 47
Detector
Length of view LD (cm) 12
Detection efficiency ,D 0.03
Atoms
Pressure P (µtorr) 35
Atomic density na (cm$3) 7 ' 1011
Binding energy (Zn) "b (eV) 0.1
Cross-sections (for Zn)
Photorecombination (d$r/d%) (cm2sr$1) 4.9 ' 10$25
Enhancement factor ( 1.1 ' 107
Stimulated recombination $sr (cm2) 5.4 ' 10$18
Expected signal rate S (s$1) 1.6 ' 10$3
Assumed values of the experimental parameters are given in table 1. Most parameters,
except those of the laser, are similar to those used in positron–molecule resonant annihilation
experiments [3]. To evaluate (d$r/d%) in equation (3), the spread in positron energies
perpendicular to the magnetic field is assumed to be a Maxwellian distribution with a
temperature kT [3], resulting in (d$r/d%) = (d$r/d%)max kT/2" where (d$r/d%)max is the
maximum cross-section value from equation (2) (i.e. at cos ' = 1). One difference in the
positron part of this experiment, as compared with the positron–molecule binding energy
measurements, is that a rotating electric field will be used to compress the beam pulses radially
by a factor of !2.5, from a radius of !7.5 to 3 mm. Based on the experience with buffer-gas
traps and positron compression using rotating electric fields, the assumption of this degree of
radial compression is probably conservative [12].
The assumed laser parameters are based on the specifications of a LaserVision optical
parametric oscillator/optical parametric amplifier pumped by a Continuum Surelite EX
Nd:YAG laser. It is capable of 12 mJ pulses at a 10 Hz rate for photon energies in the range
New Journal of Physics 14 (2012) 065004 (http://www.njp.org/)
5
from 0.35 eV (used below) to 0.8 eV. The estimates made here include an additional assumed
20% power loss due to imperfect optical elements.
As an example of a specific experiment, we consider the signal expected for zinc (Zn)
atoms with a predicted binding energy "b = 0.10 eV [1] and an estimated vapor pressure of
!3.5 ' 10$5 torr at 235 *C [13]. In this case, the positron energy at resonance is expected to
be " = 0.25 eV. Using the values in table 1, the expected signal rate is S = 0.0016 s$1. Thus,
resolving the resonant enhancement with 10 points in energy at 50 counts per point at the peak,
the expected time for a spectrum will be !3 ' 105 s, or !3.5 days. In the positron–molecule
binding measurements, it has been possible to work with similar and even smaller signal rates.
There will be a non-resonant background signal due to the so-called direct annihilation [3]
on the zinc atoms. Annihilation rates are typically expressed as a dimensionless parameter, Zeff,
which is the expected rate normalized by that expected for annihilation on a gas of free electrons
with a density equal to that of the neutral atom density. For Zn with an expected binding energy
of 0.1 eV and at an incident positron energy of 0.25 eV, Zeff ! 60 [14]. In contrast, the effective
annihilation rate when the laser is on is Zeff ! 2.2 '104.
In the relevant case of spatially overlapping positron and light beams in the viewing length
of the detector, the signal will be inversely proportional to their overlap cross-sectional area.
If either beam diameter is decreased to be less than the other, the signal will remain constant
relative to the conditions where they are equal. Since the light beam can be focused easily
to spot sizes less than !3 mm in diameter, the limiting condition will be the diameter of the
positron beam. Given previous experience in compressing plasmas with rotating electric fields,
there is probably room for improvement here, although care must be taken, even at the assumed
beam radius rp = 1.5 mm, to avoid heating the trapped positrons and hence increasing the beam
energy spread !".
With an assumed 0.35 eV photon energy, bound states in the range 0.05 < "b < 0.3 eV
can be studied, with the upper limit constrained by the magnitude of the photon energy.
The study of larger binding energies will require larger photon energies. In this case, as per
equations (2), (3) and (7), and the average (cos2 ') = kT/2", the expected signal rate depends
on photon energy as
S & "1/2b
(h̄# $ "b)$1/2
(h̄#)4
. (8)
Thus, a larger value of h̄# will result in additional degradation of the signal, and using smaller
h̄# (if a suitable laser could be found) will result in an increased signal. The signal rate S could
also be enhanced by increasing (cos2 '). Operating the annihilation cell at a larger magnetic
field than that of the positron accumulator will lead to an increase in the positron perpendicular
energy and hence could increase (cos 2').
As a (nontrivial) experimental detail, some means must be employed to carefully align
the laser and positron beams to be coincident in the viewing region of the detector. Care must
also be taken to prevent metal deposition on the optical elements in the vacuum system in the
line of sight of the hot cell (i.e. a window or mirror). This could be accomplished by heating
them to temperatures comparable to that in the hot cell. Another potential problem is ensuring
uniformity of the electrical potential of the gas cell in the presence of evaporated metal atoms.
While this would appear not to be a problem, we are not aware of experience with metal atoms
in a hot cell at the tens of millivolts level.
The technique described here might also be used to measure positron–molecule binding
energies as a complement to the present procedure of enhanced annihilation from vibrational
New Journal of Physics 14 (2012) 065004 (http://www.njp.org/)
6
Feshbach resonances [3]. For some molecules, especially polar species, the positron bound state
is not spherically symmetric. As a result, the dependence on laser polarization differs from that
in equation (2). In particular, the cross-section does not vanish when the photon polarization
is perpendicular to the incident positron momentum. Hence, the cross-section will not be
suppressed by the kT/2" as it is for atoms, and stronger signals can be expected. The cross-
section will also be enhanced for atomic and molecular species with p-wave-type bound states.
In this case, radiative capture of incident s-wave positrons is allowed, which changes the energy
dependence of the cross-section in equation (2) from !
"
" to !1/
"
" at low energies. Finally,
for atoms such as Zn and Mg, the p-wave positron has a shape resonance at low energies [15]. If
the laser energy is such that the stimulated photorecombination occurs when the positron energy
is near this resonance, the corresponding cross-section may be enhanced above the value given
in equation (2). The magnitude of this enhancement will be inversely proportional to the energy
width of the resonance.
To summarize, an experimental scenario is proposed that is capable of enabling the first
measurements of positron–atom binding energies. If successful, this and related experiments
can be expected to shed new light on the interaction of low-energy positrons with atomic and
molecular systems.
Acknowledgments
We acknowledge helpful discussions with David Cassidy. The work at the University of
California San Diego was supported by the US NSF, grant numbers PHY1068023 and
PHY1002435.
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New Journal of Physics Measuring positron-atom binding energies through laser-assisted photorecombination

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New Journal of Physics Measuring positron-atom binding energies through laser-assisted photorecombination

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