Volcanic aerosol records and tephrochronology of the Summit, Greenland, ice cores

The recently collected Greenland Ice Sheet Project 2 (GISP2) and Greenland Ice Core Project ice cores from Summit, Greenland, provide lengthy and highly resolved records of the deposition of both the aerosol (H2SO4) and silicate (tephra) components of past volcanism. Both types of data are very beneficial in developing the hemispheric to global chronology of explosive volcanism and evaluating the entire volcanism‐climate system. The continuous time series of volcanic SO42− for the last 110,000 years show a strong relationship between periods of increased volcanism and periods of climatic change. The greatest number of volcanic SO42− signals, many of very high magnitude, occur during and after the final stages of deglaciation (6000–17,000 years ago), possibly reflecting the increased crustal stresses that occur with changing volumes of continental ice sheets and with the subsequent changes in the volume of water in ocean basins (sea level change). The increase in the number of volcanic SO42− signals at 27,000–36,000 and 79,000–85,000 years ago may be related to initial ice sheet growth prior to the glacial maximum and prior to the beginning of the last period of glaciation, respectively. A comparison of the electrical conductivity of the GISP2 core with that of the volcanic SO42− record for the Holocene indicates that only about half of the larger volcanic signals are coincident in the two records. Other volcanic acids besides H2SO4 and other SO42− sources can complicate the comparisons, although the threshold level picked to make such comparisons is especially critical. Tephra has been found in both cores with a composition similar to that originating from the Vatnaöldur eruption that produced the Settlement Layer in Iceland (mid‐A.D. 870s), from the Icelandic eruption that produced the Saksunarvatn ash (∼10,300 years ago), and from the Icelandic eruption(s) that produced the Z2 ash zone in North Atlantic marine cores (∼52,700 years ago). The presence of these layers provides absolute time lines for correlation between the two cores and for correlation with proxy records from marine sediment cores and terrestrial deposits containing these same tephras. The presence of both rhyolitic and basaltic shards in the Z2 ash in theGISP2 core and the composition of the basaltic grains lend support to multiple Icelandic sources (Torfajökull area and Katla) for the Z2 layer. Deposition of the Z2 layer occurs at the beginning of a stadial event, further reflecting the possibility of a volcanic triggering by the effects of changing climatic conditions

Planning for Sustainability in Small Municipalities: The Influence of Interest Groups, Growth Patterns, and Institutional Characteristics

How and why small municipalities promote sustainability through planning efforts is poorly understood. We analyzed ordinances in 451 Maine municipalities and tested theories of policy adoption using regression analysis.We found that smaller communities do adopt programs that contribute to sustainability relevant to their scale and context. In line with the political market theory, we found that municipalities with strong environmental interests, higher growth, and more formal governments were more likely to adopt these policies. Consideration of context and capacity in planning for sustainability will help planners better identify and benefit from collaboration, training, and outreach opportunities

Observing biogeochemical cycles at global scales with profiling floats and gliders: prospects for a global array

Chemical and biological sensor technologies have advanced rapidly in the past five years. Sensors that require low power and operate for multiple years are now available for oxygen, nitrate, and a variety of bio-optical properties that serve as proxies for important components of the carbon cycle (e.g., particulate organic carbon). These sensors have all been deployed successfully for long periods, in some cases more than three years, on platforms such as profiling floats or gliders. Technologies for pH, pCO2, and particulate inorganic carbon are maturing rapidly as well. These sensors could serve as the enabling technology for a global biogeochemical observing system that might operate on a scale comparable to the current Argo array. Here, we review the scientific motivation and the prospects for a global observing system for ocean biogeochemistry

A review of Central Asian glaciochemical data

The glaciers of central Asia provide suitable locations from which to recover continuous, high-resolution glaciochemical records on a continental scale. Although the glaciochemical investigations undertaken to date in central Asia are few in number and limited in terms of spatial coverage and length of record, some preliminary observations can be made concerning regional and seasonal trends in snow chemistry in this region. The sodium chloride ratio for most snow samples collected in central Asia approaches the ratio found in sea water (0.86 in /Leq kg-I ), reflecting a marine source for these constituents. Sodium and chloride concentrations are, on average, 3-10 times higher in the Himalayas than in the Karakoram, demonstrating the greater influence of monsoonal sources of moisture in the Himalayas. Very high sodium concentrations from Khel Khod Glacier probably reflect a local crustal source from surrounding ice-free areas. Low nitrate concentrations were found in snow collected from the southern margin of the Himalayas and high concentrations in snow deposited on the north margin of the Himalayas. This strong regional trend in the spatial distribution of nitrate suggests the influx of continental aerosols, rich in nitrate, originating from the arid regions of central Asia. High calcium concentrations measured in snow from Mount Everest and the north-west corner of China are also indicative of dust derived from the arid regions of central Asia. Very high sulfate concentrations found in snow from the Tien Shan and the Bogda Shan most likely reflect local anthropogenic sources. The altitude effect on isotopic composition is not apparent from snow samples collected in central Asia. Understanding the processes which control the chemical content of snow, the local-to-regional scale complexities, and the seasonal variability are fundamental steps necessary to assess the potential for recovering representative long-term glaciochemical records from central Asia

Global perspective of nitrate flux in ice cores

The relationships between the concentration and the flux of chemical species (Cl-, NO3 - , SO42-, Na +, K + , NH4 + , Mg 2+ , Ca 2+) versus snow accumulation rate were examined at GISP2 and 20D in Greenland, Mount Logan from the St. Elias Range, Yukon Territory, Canada, and Sentik Glacier from the northwest end of the Zanskar Range in the Indian Himalayas. At all sites, only nitrate flux is significantly (a = 0.05) related to snow accumulation rate. Of all the chemical series, only nitrate concentration data are normally distributed. Therefore we suggest that nitrate concentration in snow is affected by postdepositionaJ exchange with the atmosphere over a broad range of environmental conditions. The persistent summer maxima in nitrate observed in Greenland snow over the entire range of record studied (the last 800 years) may be mainly due to NO• released from peroxyacetyl nitrate by thermal decomposition in the presence of higher OH concentrations in summer. The late winter/early spring nitrate peak observed in modern Greenland snow may be related to the buildup of anthropogenically derived N Oy in the Arctic troposphere during the long polar winter

A 110,000‐year history of change in continental biogenic emissions and related atmospheric circulation inferred from the Greenland Ice Sheet Project Ice Core

The 110,000‐year record of ammonium concentrations from the Greenland Ice Sheet Project 2 (GISP2) ice core provides the basis for an analysis of terrestrial biological production and atmospheric circulation patterns involved in the transport of biologically produced ammonium to the Greenland atmosphere. The directly measured concentration series was selected for analysis, rather than that of estimated ammonium flux, after a detailed analysis of the relationship among ice core glaciochemical concentrations and a high‐resolution simultaneous record of snow accumulation from the GISP2 core. Analysis of the ammonium concentration series shows that maxima in background levels of ammonium in the Greenland atmosphere are strongly related to and synchronous with summer forcing associated with the precessional cycle of insolation. Minima in background levels, on the other hand, are delayed relative to minima in summer insolation at those times when ice volume is significant. The duration of these delays are similar in magnitude (≈6000 years) to other paleoclimatic responses to changes in ice volume. Decadal and centennial scale variation about background levels of ammonium concentration exhibit two modes of behavior when compared to a record of polar atmospheric circulation intensity. During warmer periods ammonium transport to Greenland is similar to present patterns. Under coldest conditions the low levels of ammonium transported to Greenland are the result of extreme southerly excursions of the predominantly zonal polar circulation. The rapid transitions (≈200 years) between these two climatic conditions appear to be associated with a critical volume or extent of the continental ice sheets

Potential atmospheric impact of the Toba Mega‐Eruption ∼71,000 years ago

An ∼6‐year long period of volcanic sulfate recorded in the GISP2 ice core about 71,100 ± 5000 years ago may provide detailed information on the atmospheric and climatic impact of the Toba mega‐eruption. Deposition of these aerosols occur at the beginning of an ∼1000‐year long stadial event, but not immediately before the longer glacial period beginning ∼67,500 years ago. Total stratospheric loading estimates over this ∼6‐year period range from 2200 to 4400 Mt of H2SO4 aerosols. The range in values is given to compensate for uncertainties in aerosol transport. Magnitude and longevity of the atmospheric loading may have led directly to enhanced cooling during the initial two centuries of this ∼1000‐year cooling event