Efficiency Analysis of LOHC Based Hydrogen Energy Storage System

有机液体储氢材料是理想的储氢介质。本文建立了以有机液体储氢材料为基础的氢储能系统的能效分析模型,并以乙基咔唑和二苄基甲苯两种有机液体储氢载体为算例,逐步计算了制氢、储氢和燃料电池等过程的能耗。研究结果表明,乙基咔唑能效优于二苄基甲苯,其储氢效率为84.17%、系统能效为47.58%。本研究所开发的框架可衡量基于有机液体储氢载体的氢储能系统的能效,并可用于筛选有机液体储氢载体

Material and Energy Conversion of Integrated 100,t/a-Scale Bio-Jet Fuel-Range Hydrocarbon Production System via Aqueous Conversion of Biomass

以农业废弃物生物质为原料，利用水相转化技术，进行了百吨/年规模生物航油类烃(C8~C15)合成试运行.过程中采用两步酸解法分别将玉米秸秆中半纤维素和纤维素转化为糠醛和乙酰丙酸，作为生物质基平台化合物.在碱性条件下糠醛与乙酰丙酸经Aldol缩合反应实现碳链增长，生成的长链含氧中间体经过低温预加氢、高温加氢脱氧及精制，生成C8~C15范围内液态烃，可作为生物航油组分.以试运行实验结果为基础，进行了过程的物质与能量转化分析.结果表明，该路线获得液态烃类的基本性质满足合成航油ASTM-7566标准要求，并充分利用了原料中纤维素和半纤维素组分，是一条基于生物质的长链液态烃合成路线，1t航油约需10~12t干基玉米秸秆

Effect of ZnF2 Coating on Performance of LiNi0.5Mn1.5O4 Cathode Material for Lithium-ion Batteries

采用溶胶-凝胶法制备了LiNi0.5Mn1.5O4正极材料，并利用Zn F2对其表面进行包覆改性。XRD、SEM和TEM测试表明，包覆处理不影响材料的晶体结构，2%(质量分数，以LiNi0.5Mn1.5O4质量计，下同)的Zn F2在LiNi0.5Mn1.5O4表面形成了约7 nm厚均匀包覆层。对未包覆的LiNi0.5Mn1.5O4和1%、2%、3%的Zn F2包覆后的LiNi0.5Mn1.5O4的电化学性能进行了考察，发现Zn F2包覆能够减弱电解液与LiNi0.5Mn1.5O4正极材料之间的相互作用，稳定电极表面，提高材料的电化学性能。其中，2%Zn F2包覆样品表现出最佳的循环性能和倍率性能，0.2C电流倍率下循环200圈后，其放电比容量维持在109.0 m A·h/g，保持率为79.7%；5 C电流倍率下循环500圈后，放电比容量维持在94.2 m A·h/g，保持率为85.6%

甘孜地热发电热力计算及优化

A geothermal well in Ganzi was chosen for the study. To provide a reference for the design and construc?tion of a geothermal plant, power generation techniques were selected and the thermodynamic process was calculat?ed based on cold and heat source dat

Research Progress on Hybrid Solar-Geothermal Power Generation

Developing and using combined new energy sources is an important direction of development for new energy in future. The first Hybrid Solar-Geothermal Power station has been built, and related research on this field has been carried out vigorously. Accord

Numerical study of vapor bubble effect on flow and heat transfer in microchannel

Flow boiling in a microchannel is characterized by nucleation and dynamic behavior of vapor bubbles in the channel. In the present study, the effect of vapor bubble on fluid flow and heat transfer in a microchannel is investigated via lattice Boltzmann (LB) modeling. With respect to boiling flow in a single microchannel, the bubble nucleation, growth, and departure are simulated by using an improved hybrid LB model. Relating bubble behavior with fluid flow and boiling heat transfer provides some insight into the relevant fundamental physics on flow boiling in the microchannel. It is found that the bubble growth before its departure from the wall induces an obvious resistance to the fluid flow. The processes of nucleation and motion of different bubbles interact, leading to an alternate, either enhanced or weakened, effect of bubble behavior on the flow boiling. (C) 2011 Elsevier Masson SAS. All rights reserved.</p

Gas Production from Methane Hydrate in a Pilot-Scale Hydrate Simulator Using the Huff and Puff Method by Experimental and Numerical Studies

A novel three-dimensional 117.8-L pressure vessel, which is called a Pilot-Scale Hydrate Simulator (PHS), is developed to investigate the gas production performance from hydrate-bearing porous media using the huff and puff method through both experimental and numerical simulations. The methane gas and deionized water are injected into the pressure vessel to synthesize methane hydrate. The grain sizes of the quartz sand in the vessel are between 300 and 450 mu m. The huff and puff stages, including the injection, the soaking, and the production, are employed for hydrate dissociation. A single vertical well at the axis of the PHS is used as the injection and production well. The whole experiment consists of 15 huff and puff cycles. The numerical simulation results agree well with the experiment. Both the experimental and numerical simulation results indicate that the injected water is mainly restricted around the well during the injection stage. The system pressure fluctuates regularly in each cycle, and the secondary hydrate is formed under the pressurization effect caused by the hot water injection in the injection stage. The gas production rate maintains approximately stable in a relatively long period. The sensitivity analysis indicates that the gas production can be enhanced with high intrinsic permeability of the deposit or by raising the temperature of the injected hot water. The mass of the water produced in each cycle has little difference and is manageable when using the huff and puff method.</p

Research progress in Li-ion battery pack inconsistency control

总结电池均衡、成组方式和热管理的研究方法及问题。电池均衡技术主要有电池均衡电路、电池均衡控制策略；电池成组方式主要有电池串并联方式、电池连接阻抗；电池热管理主要有电池生热特性、电池散热结构和电池组热管理等

SDS effect on formation kinetics and microstructure of methane hydrate

表面活性剂是促进水合物生成的有效手段之一。在高压反应釜中研究了十二烷基硫酸钠(SDS)对水合物生成过程的动力学影响，利用XRD和拉曼光谱探究了SDS存在条件下水合物的微观结构。宏观结果表明SDS缩短了诱导时间，加快了水合物生长速率。微观结果表明SDS没有影响s I型水合物的晶型结构，晶面间距与理想s I型水合物及纯水甲烷对比误差在千分之几。水合物中甲烷在大笼小笼中的拉曼位移分别为2904和2915 cm-1，SDS没有改变大笼小笼结构。大笼绝对占有率(?L)接近饱和时，SDS可以进一步提高小笼绝对占有率(?S)，从微观角度证明了SDS可以减少水合数，提高储气率