THE EFFECT OF TITLE I OF THE 1949 FEDERAL HOUSING ACT ON NEW YORK CITY COOPERATIVE AND CONDOMINIUM CONVERSION PLANS

In 1985, three Manhattan housing projects were in litigation to convert the units from rental to condominiums or cooperative ownership. However, each project\u27s redevelopment agreement, consistent with Title I of the 1949 Federal Housing Act, required that no change be made without consent of the City Planning Commission and the Board of Estimates of the City. This Note analyzes whether the conversion of rental units built under Title I to ownership units constitutes a change as interpreted by the New York courts. The interpretation of the term change under the Title I redevelopment agreements will be analyzed from both the City of New York\u27s and the private developer\u27s views. In addition, the legislative purposes behind Title I\u27s enactment will be examined from the perspectives of both the City of New York and the private developer. Finally, the current status of Title I will be discussed. This Note concludes that a change, for purposes of New York City redevelopment agreements drafted pursuant to Title I, refers only to land use and density and does not relate to the form of ownership. Therefore, city approval should not be required for a Title I building to convert to condominium or cooperative status

THE CREATIVE RATIONALITY AS A KEY DRIVER FOR ENHANCING INNOVATION CAPABILITY

Several recent works point out that design is one of the main driver of innovation. Therefore, it is interesting to analyze how design contributes to these last process. The point of view we present in this communication assumes that design is based on a specific rational we called creative rationality. This paper aims at presenting its theoretical roots. Creative rationality derives from Vico's notion of Ingenium. Creative rationality explains the creation of new artifacts and knowledge by knoting in a ingenious way scattered knowledge. It depends on several cognitive, individual and social variables one can identify, measure, and combine in a unified model.Design, creativity, innovation, creative rationality.

Estimated carboxylic acid ester hydrolysis rate constants for food and beverage aroma compounds

Aroma compounds in the Flavornet database were screened for potentially hydrolyzable carboxylic acid ester functionalities. Of the 738 aroma compounds listed in this database, 140 molecules contain carboxylic acid ester groups that may be amenable to hydrolysis in various food and beverage products. Acid- (k~A~) and base- (k~B~) catalyzed and neutral (k~N~) hydrolysis rate constants in pure water at 25°C were estimated for these aroma compounds. Where available, good agreement between theoretical and experimental hydrolytic half-lives was obtained at various pH values. Wide ranges and broad frequency distributions for k~A~, k~B~, and k~N~ are expected among the various hydrolyzable aroma compounds, with estimated k~A~ ranging from 3.7×10^-8^ to 4.7×10^-4^ M^-1^ s^-1^, estimated k~B~ ranging from 4.3×10^-4^ to 43 M^-1^ s^-1^, and estimated k~N~ ranging from 4.2×10^-17^ to 7.6×10^-9^ M^-1^ s^-1^. The resulting hydrolytic half-lives also range widely, from 10 days to 370 years at pH 2.8, 18 days to 4,900 years at pH 4.0, 1.8 days to 470 years at pH 7.0, and 26 minutes to 5.1 years at pH 9.0. The findings presented herein attest to the importance of considering abiotic hydrolysis and matrix pH when modeling the evolution of sensory characteristics for foods and beverages with carboxylic acid ester based aroma compounds

Absence of historical temporal trends in monthly, seasonal, and annual streamflows for the Okanagan and Similkameen Rivers in south-central British Columbia, Canada

Potential historical temporal trends in monthly, seasonal, and annual mean, minimum, and maximum streamflows and date of the spring freshet runoff peak were investigated for the Okanagan and Similkameen Rivers in south-central British Columbia, Canada. There appears to be no compelling evidence that streamflow patterns in the Okanagan and Similkameen Rivers have changed over the available hydrometric record, nor does there appear to be evidence that future changes in streamflow patterns are imminent or likely

Historical Trends in Annual Water Yields for the Okanagan Basin, British Columbia, Canada

The Okanagan Basin in south-central British Columbia, Canada, includes the Okanagan River watershed upstream from the outlet of Osoyoos Lake, with a total area of 8,046 km^2^. Over the past century, the population of the Basin has grown rapidly, and this trend is expected to continue. Water management issues attract significant attention in the region, given projected declines in supply and increases in demand. Historical streamflow data was obtained for three hydrometric stations on the Okanagan River between the outlet of Okanagan Lake at Penticton and near the U.S. border at Oliver. Collectively, the historical data series indicate no temporal changes in regional annual water yields for the Okanagan Basin over the past century, despite large increases in population and agricultural activity over this time. Although rapid and extensive human settlement and development of the region, along with possible climate change signatures during the 20th century, has potentially altered the inflow hydrographs to tributary streams in the Basin, the overall water yield of the region appears to be stable and possibly increasing

Structures, enthalpies of formation, and ionization energies for the parent and binary mixed carbon, silicon, nitrogen, and phosphorus cubane derivatives: A G4MP2 theoretical study

Gas phase standard state (298.15 K, 1 atm) structures, enthalpies of formation, and ionization energies (IEs) were calculated at the G4MP2 composite method level of theory for the parent and binary mixed carbon, silicon, nitrogen, and phosphorus cubane derivatives. Increasing nitrogen content increases the enthalpies of formation for the carbon-nitrogen, nitrogen-phosphorus, and silicon-nitrogen binary cubanes, with the opposite enthalpies of formation trend for increasing phosphorus content within the carbon-phosphorus, nitrogen-phosphorus, and silicon-phosphorus derivatives. Varying carbon/silicon content in the carbon-silicon cubanes results in no general trends for enthalpies of formation. Isomerization enthalpies within the homolog groups having more than one isomer vary widely with atomic composition and substitution patterns. Increasing nitrogen content of the carbon-nitrogen and nitrogen-phosphorus derivatives increases the IE, increasing silicon content in the carbon-silicon cubanes and phosphorus content of the carbon-phosphorus cubanes decreases the IE, while no IE clear trends are evident based on relative atomic content for the silicon-nitrogen and silicon-phosphorus compounds. The binary mixed carbon, silicon, nitrogen, and phosphorus cubane derivatives are predicted to display potentially tunable thermodynamic stability and redox behavior depending on the atom identities and relative positions

Historical temporal trends in monthly, seasonal, and annual mean, minimum, and maximum streamflows from the Okanagan River watershed in south-central British Columbia, Canada

Historical trends in monthly, seasonal, and annual mean streamflows, as well as minimum and maximum monthly streamflows, were investigated at nine hydrometric stations in the Okanagan River watershed from south-central British Columbia, Canada. Overall, mean annual streamflows in the Okanagan River watershed are not exhibiting any significant time trends. No consistent declines in monthly minimum streamflows are evident at any point during the hydrologic year. Mean monthly and monthly maximum streamflows in tributary streams to the mainstem system appear to be significantly increasing over time during the spring snowmelt period of March and April. Any temporal changes in flow patterns at the mainstem Okanagan River stations likely reflect alterations in water management strategies over time at the respective upstream dams