Synthesis and in situ transformation of PST-1: a potassium gallosilicate natrolite with a high Ga content

Supplementary material included at the end of the file. Material suplementario incluido al final del archivo.The synthetic details of a novel potassium gallosilicate natrolite with Si/Ga = 1.28, denoted PST-1, are described. The presence of K+ and Ga with well-defined levels of concentration in the synthesis mixture is essential for directing its crystallisation. PST-1 transforms rapidly into TNU-6 under hydrothermal conditions, behaviour that contrasts sharply with its very high thermal and hydrothermal stability, which is unusual for a material of such a high Ga content. These stability issues are discussed and rationalized based on chemical composition, likely violations of Loewenstein’s rule and the temperature of dehydration of as-made K-PST-1. The crystal structure of TNU-6 has been resolved through the combined use of synchrotron X-ray and electron diffraction data; it has the BaFeGaO4 structure type with an additional √3a x √3a “GeAlO4” superstructure that arises from tilting of some of the tetrahedral units in all of the 6-rings.Dalton Transactions 2010, 39, 2246-2253KOSEF through the National Research Laboratory Program (R0A-2007-000-20050-0).Peer reviewe

Synthesis and in situ transformation of PST-1: a potassium gallosilicate natrolite with a high Ga content

The synthetic details of a novel potassium gallosilicate natrolite with Si/Ga = 1.28, denoted PST-1, are described. The presence of K+ and Ga with well-defined levels of concentration in the synthesis mixture is essential for directing its crystallisation. PST-1 transforms rapidly into TNU-6 under hydrothermal conditions, behaviour that contrasts sharply with its very high thermal and hydrothermal stability, which is unusual for a material of such a high Ga content. These stability issues are discussed and rationalized based on chemical composition, likely violations of Loewenstein's rule and the temperature of dehydration of as-made K-PST-1. The crystal structure of TNU-6 has been resolved through the combined use of synchrotron X-ray and electron diffraction data; it has the BaFeGaO4 structure type with an additional root 3a x root 3a "GeAlO4" superstructure that arises from tilting of some of the tetrahedral units in all of the 6-rings.open114sciescopu