Dual role of copper on the reactivity of activated carbons from coal and lignocellulosic precursors

The synthesis of copper-doped activated carbons from different origin (i.e., lignocellulosic and bituminous coal) by a wet impregnation and low temperature calcination procedure has been explored, as well as the role of copper particles on the physicochemical and structural features of the resulting materials. The textural characterization and isothermal reactivity analysis of the pristine and doped activated carbons have shown that the role of copper during the calcination step strongly depended on the nature of the carbon matrix. Copper impregnation of a coal-derived activated carbon catalyzed the air gasification of the material at a very low temperature (i.e., 325 °C), bringing about the development of microporosity on the doped carbon. In contrast, when copper was immobilized on a lignocellulose-derived activated carbon, the metallic species act as combustion retardant during the calcination step, protecting the carbon matrix during the catalytic gasification. In both cases, the resulting materials displayed a homogenous distribution of copper within the carbon matrix, while preserving large textural properties.The authors thank the Spanish MICINN for financial support (projects CTM2008-01956/TECNO and Acción Integrada AIB2010PT-00209). MH thanks CSIC for a postdoctoral contract. MA thanks FCT for her PhD fellowship (SFRH/BD/71673/2010). The authors also thank Cordex for kindly providing the sisal residues.Peer reviewe

Dual role of copper on the reactivity of activated carbons from coal and lignocellulosic precursors

International audienc