Enhancement of mechanical and thermoelectric properties of Ca3Co4O9 by Ag addition

Ca3Co4O9 + x wt.% Ag (x = 0, 1, 3, 5, and 10) polycrystalline thermoelectric ceramics have been prepared by a sol–gel route via nitrates followed by high temperature treatment before sintering. Out-of-plane XRD data have shown that major phase is the Ca3Co4O9 one, accompanied by metallic Ag. SEM observations have agreed with the XRD data. Apparent density measurements have revealed that all samples possess densities ranging between 80% and 90% when Ag content is raised. Mechanical properties have shown a drastic increase of bending stress when Ag is added to the samples. Electrical resistivity decreases with the Ag content, compared with the pure ones, while Seebeck coefficient slightly decreases. Maximum power factor values around 0.43 mW/K2 m at 800 °C have been achieved for the 10 wt.% Ag samples which is much higher than the measured in the pure Ca3Co4O9 samples.This research has been supported by MINECO-FEDER (MAT2013-46505-C3-1-R). The authors wish to thank the Gobierno de Aragón-Fondo Social Europeo (Consolidated Research Groups T12 and T87) for financial support.Peer Reviewe