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    Experimental investigation and model validation of a CaO/Ca(OH)2 fluidized bed reactor for thermochemical energy storage applications

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    The CaO/Ca(OH)2 hydration/dehydration chemical loop has long been recognized as a potential candidate for application in energy storage systems for concentrated solar plants. However, the technology still remains at a conceptual level because little information has been published on the performance of the key reactors in the system. In this work, we experimentally investigate the hydration and dehydration reactors in a 5.5 kWth batch fluidized bed reactor, in conditions relevant to larger systems (superficial gas velocities of up to 0.53 m/s, temperatures of up to 500°C for dehydration, input H2O(v) fractions between 0 and 0.8 etc.). Furthermore, to assist in the interpretation of the experimental results, a standard 1D bubbling reactor model has been formulated and fitted to the experimental results by including kinetic information at particle level independently measured in a thermogravimetric apparatus. The results indicate that the hydration reaction is mainly controlled by the slow kinetics of the CaO material tested while significant emulsion-bubble mass-transfer resistances were identified during dehydration due to the much faster dehydration kinetics.The financial support provided by the European Commission under the 7th Framework Program (StoRRe Project GA 282677) is acknowledged. Y.A. Criado thanks the Government of the Principality of Asturias for a Ph.D. fellowship (Severo Ochoa Program).Peer reviewe
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