Corrosion product layers on magnesium alloys AZ31 and AZ61: Surface chemistry and protective ability

This paper studies the chemical composition of the corrosion product layers formed on magnesium alloys AZ31 and AZ61 following immersion in 0.6M NaCl, with a view to better understanding their protective action. Relative differences in the chemical nature of the layers were quantified by X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), energy dispersive analysis of X-ray (EDX) and low-angle X-ray diffraction (XRD). Corrosion behavior was investigated by Electrochemical Impedance Spectroscopy (EIS) and hydrogen evolution measurement. An inhibitive effect from the corrosion product layers was observed from EIS, principally in the case of AZ31, as confirmed by hydrogen evolution tests. A link was found between carbonate enrichment observed by XPS in the surface of the corrosion product layer, concomitant with the increase in the protective properties observed by EIS.We would like to express our gratitude to Professor S. Feliu for numerous clarifying and stimulating discussions during the course of this research. The authors also gratefully acknowledge the financial support for this project from the Spanish Ministry of Economy and Competitiveness (MAT 2009-13530)Peer Reviewe