Bimetallic Au//Ag alloys inside SiO2 using a solid state method

Bimetallic Au/Ag nanostructures have been included inside SiO2 by pyrolysis of the macromolecular complexes Chitosan center dot(MLn/M'Ln)(n)center dot SiO2 and PSP-4-PVP center dot(MLn/M'Ln)(n)center dot SiO2 with MLn = AuCl3 and M'Ln = Ag(CF3SO3). The structural characterization was performed by XRD (X-ray diffraction of powder) and UV-Vis, and the microstructural characterization was done by SEM/EDS analysis HRTEM. The resulting products from the pyrolytic precursors PSP-4-PVP center dot(AuCl3/AgSO3CF3)(n)center dot SiO2 1:1 (1), PSP-4-PVP center dot(AuCl3/AgSO3CF3)(n)center dot SiO2 1:5 (2), Chitosan center dot(AuCl3/AgSO3CF3)(n)center dot SiO2 1:1 (3) and Chitosan center dot(AuCl3/AgSO3CF3)(n)center dot SiO2 1:5 (4) were Au/Ag//SiO2, Au//SiO2 and Ag//SiO2 as well as isolated Au and Ag, depending on the polymeric precursor. The Chitosan polymer precursor induces mainly Ag and Ag/SiO2 nanostructures, while PSP-4-PVP induces mainly Au/Ag//SiO2 nanostructures. This can be explained by the facility to link Ag+ to the NH2 and OH groups of Chitosan than to the pyridine of PSP-4-PVP. On the contrary, Au3+ exhibits most coordination ability to pyridine groups of PSP-4-PVP than NH2- and OH-groups of Chitosan. EDS mapping analysis indicates a uniform distribution of the Au/Ag nanostructure inside the SiO2 matrix. Using reflectance diffuse analysis, the plasmon is consistent with the Au/Ag alloys structure.Fondecyt 1120179 1160241 1131112 Consejo Superior de Investigaciones Cientificas, Spain I-COOP LIGHT 2015CD001