Proton modified Pt zeolite fuel cell electrocatalysts

NaY Zeolite is selected as a suitable material to host 1.5 wt% Platinum (Pt) loading on zeolite using ion exchange method (a) Pt(NH3)4(NO3)2 without excess NH4NO3 nitrate and (b) Pt(NH3)4(NO3)2 with excess NH4NO3 nitrate. The structure/reactivity relationship of Pt nanoparticle has been experimentally studied via Nafion@ bound electrodes to investigate the interaction nature of Pt with zeolite and electron transfer using the extended X-ray adsorption fine structure (EXAFS) and Pt particle was predicted at 0.7 – 1.5 (nm). Pt oxides can be electrochemically reduced via a hydrogen ‘spillover’ phenomenon. A highly dispersed small Pt particle distribution can be achieved with excessive H+ ions on zeolite acidic sites

Time crystals in periodically driven systems

When the discrete time-translation symmetry of isolated, periodically driven systems is spontaneously broken, a new phase of matter can emerge. We review some recent developments on both the theoretical underpinnings and experimental realizations of time crystalline order. Particular attention is placed on delineating the key features of time crystals, which distinguish them from other oscillatory non-equilibrium phenomena.Comment: 7 pages, 5 figures, 1 tabl

Final stare interaction enhancement effect on the near threshold p\bar p system in B^\pm\to p\bar p \p^\pm decay

We discuss the low-mass enhancement effect in the baryon-antibaryon invariant mass in three-body baryonic B decays using final state interactions in the framework of Regge theory. We show that the rescattering between baryonic pair can reproduce the observed mass spectrum.Comment: 7 pages, 11 figure

Systematic study of the symmetry energy coefficient in finite nuclei

The symmetry energy coefficients in finite nuclei have been studied systematically with a covariant density functional theory (DFT) and compared with the values calculated using several available mass tables. Due to the contamination of shell effect, the nuclear symmetry energy coefficients extracted from the binding energies have large fluctuations around the nuclei with double magic numbers. The size of this contamination is shown to be smaller for the nuclei with larger isospin value. After subtracting the shell effect with the Strutinsky method, the obtained nuclear symmetry energy coefficients with different isospin values are shown to decrease smoothly with the mass number $A$ and are subsequently fitted to the relation $\dfrac{4a_{\rm sym}}{A}=\dfrac{b_v}{A}-\dfrac{b_s}{A^{4/3}}$. The resultant volume $b_v$ and surface $b_s$ coefficients from axially deformed covariant DFT calculations are $121.73$ and $197.98$ MeV respectively. The ratio $b_s/b_v=1.63$ is in good agreement with the value derived from the previous calculations with the non-relativistic Skyrme energy functionals. The coefficients $b_v$ and $b_s$ corresponding to several available mass tables are also extracted. It is shown that there is a strong linear correlation between the volume $b_v$ and surface $b_s$ coefficients and the ratios $b_s/b_v$ are in between $1.6-2.0$ for all the cases.Comment: 16 pages, 6 figure