287 research outputs found
SPARC Data Initiative: climatology uncertainty assessment
The SPARC Data Initiative aims to produce trace gas climatologies for a number of species from a number of instruments. In order to properly compare these climatologies, and interpret differences between them, it is necessary to know the uncertainty in each calculated climatological mean field. The inhomogeneous and finite temporal-spatial sampling pattern of each instrument can lead to biases and uncertainties in the mean climatologies. Sampling which is unevenly weighted in time and space leads to biases between a data set's climatology and the truth. Furthermore, the systematic sampling patterns of some instruments may mean that uncertainties in mean fields calculated through traditional methods that assume random sampling may be inappropriate. We aim to address these
issues through an exercise wherein high resolution chemical fields from a coupled Chemistry Climate Model are sub-sampled based on the sampling pattern of each instrument. Climatologies based on the sub-sampled data can be compared to those calculated with the full data set, in order to assess sampling biases. Furthermore, investigating the ensemble variability of climatologies based on subsampled fields will allow us to assess the proper methodology for estimating the uncertainty in climatological mean fields
Factors affecting symbolic and use adoption of local foods for consumers in Black Hawk County, Iowa
A local food system may be an alternative to the increasingly globalized and concentrated food market and a means to augment the availability of fresh foods, create economically viable options for farmers and enhance the health of local ecosystems. Consumers are a vital component of these systems. Insight into the decision-making process surrounding the purchase of local foods can aid in efforts to build thriving local food systems. Studies on consumer attitudes show that, in general, consumers are aware and supportive of local foods. Abstract or civic factors, such as concern for the environment or food safety, are often identified as predictive characteristics. Results conflict, however, as to the influence of traditional demographic factors. This study analyzed telephone survey data of consumers in Black Hawk County, Iowa. Causative factors are evaluated within the context of a two-phase decision-making model, which distinguishes symbolic adoption, the acceptance of an idea, from use adoption, the behavioral practice of the idea. Testable variables are grouped as either sociological/civic or expediency factors. Sociological/civic factors include social demographic variables in addition to civic concerns. Expediency factors include measures of time constraints and economic variables. It is hypothesized that sociological/civic factors are relatively more important than expediency factors in symbolic adoption of local foods, and these factors must interact positively with expediency factors for use adoption to occur. Final multivariate regression models are derived. A two-stage least squares approach is used to incorporate the final prediction model for symbolic adoption into that for use adoption. Results show that sociological/civic factors are relatively more important to symbolic adoption than expediency factors, particularly the civic factors of having concerns about food safety, following environmental issues and knowing a farmer. Use adoption is more likely if appropriate interactions with the expediency variables of price-consciousness and income take place. For symbolic adopters, lower price-consciousness and lower incomes lead to an increased tendency to buy local foods. For those not indicating symbolic adoption, opposite effects occur. For both groups, a complementary interplay with the sociological factors of educational level and knowing a farmer also influences use adoption
Spatial and temporal pulse shaping for lateral and depth resolved two-photon excited fluorescence contrast
We report combined temporal and spatial laser pulse shaping to perform lateral and depth dependent two-photon excited fluorescence of dyes. For generating the specific spatially and temporally phase tailored pulses a temporal pulse shaper and a subsequent spatial pulse shaper are employed. Simultaneous spatial and temporal shaping is presented for two-photon excited fluorescence by applying temporal third order phase functions on spatially different light field components. Moreover, the prospects of spatial shaping are demonstrated by applying various lateral two-photon fluorescence pattern. In particular, a depth dependent excitation of different dyes is performed which leads to a high axially resolved fluorescence contrast. The introduced spatial and temporal shaping technique provides new perspectives for biophotonic imaging applications
Production of Plant Extracts – from Evolution to Revolution Resource Efficient Manufacturing in Regulated Industries
Community Supported Agriculture (CSA) in the Midwest United States: A regional characterization
This report analyzes information from a survey of nearly 150 CSAs in nine Midwestern states
Combined temporal and spatial laser pulse shaping for two-photon excited fluorescence contrast improvement
We report on combined simultaneous temporal and spatial laser pulse shaping by utilizing light polarization properties. Thereto, a setup comprising a temporal pulse shaper, a waveplate, and a spatial shaper was developed and characterized by comparison with simulations. This enables to simultaneously shape one polarization component temporally and spatially while the perpendicular polarization component is modified temporally. The spatially and temporally modulated light fields were recorded and visualized by suitable contour plots, which was particularly demonstrated for cylindrically symmetric pulse profiles. Moreover, temporally and spatially shaped pulses were applied for two-photon excited fluorescence of dyes. These measurements were conducted by scanning third order phase functions for specific spatial pulse components which yields an enhanced contrast difference between fluorescing dyes. The presented temporal and spatial shaping method of ultrashort laser pulses has a high potential for biophotonic applications
Modelling marine emissions and atmospheric distributions of halocarbons and dimethyl sulfide: the influence of prescribed water concentration vs. prescribed emissions
Marine-produced short-lived trace gases such as dibromomethane (CH2Br2), bromoform (CHBr3), methyliodide (CH3I) and dimethyl sulfide (DMS) significantly impact tropospheric and stratospheric chemistry. Describing their marine emissions in atmospheric chemistry models as accurately as possible is necessary to quantify their impact on ozone depletion and Earth's radiative budget. So far, marine emissions of trace gases have mainly been prescribed from emission climatologies, thus lacking the interaction between the actual state of the atmosphere and the ocean. Here we present simulations with the chemistry climate model EMAC (ECHAM5/MESSy Atmospheric Chemistry) with online calculation of emissions based on surface water concentrations, in contrast to directly prescribed emissions. Considering the actual state of the model atmosphere results in a concentration gradient consistent with model real-time conditions at the ocean surface and in the atmosphere, which determine the direction and magnitude of the computed flux. This method has a number of conceptual and practical benefits, as the modelled emission can respond consistently to changes in sea surface temperature, surface wind speed, sea ice cover and especially atmospheric mixing ratio. This online calculation could enhance, dampen or even invert the fluxes (i.e. deposition instead of emissions) of very short-lived substances (VSLS). We show that differences between prescribing emissions and prescribing concentrations (−28 % for CH2Br2 to +11 % for CHBr3) result mainly from consideration of the actual, time-varying state of the atmosphere. The absolute magnitude of the differences depends mainly on the surface ocean saturation of each particular gas. Comparison to observations from aircraft, ships and ground stations reveals that computing the air–sea flux interactively leads in most of the cases to more accurate atmospheric mixing ratios in the model compared to the computation from prescribed emissions. Calculating emissions online also enables effective testing of different air–sea transfer velocity (k) parameterizations, which was performed here for eight different parameterizations. The testing of these different k values is of special interest for DMS, as recently published parameterizations derived by direct flux measurements using eddy covariance measurements suggest decreasing k values at high wind speeds or a linear relationship with wind speed. Implementing these parameterizations reduces discrepancies in modelled DMS atmospheric mixing ratios and observations by a factor of 1.5 compared to parameterizations with a quadratic or cubic relationship to wind spee
Retrieving wind statistics from average spectrum of continuous-wave lidar
The aim of this study is to experimentally demonstrate that the time-average Doppler spectrum of a continuous-wave (cw) lidar is proportional to the probability density function of the line-of-sight velocities. This would open the possibility of using cw lidars for the determination of the second-order atmospheric turbulence statistics. An atmospheric field campaign and a wind tunnel experiment are carried out to show that the use of an average Doppler spectrum instead of a time series of velocities determined from individual Doppler spectra significantly reduces the differences with the standard deviation measured using ordinary anemometers, such as ultra-sonic anemometers or hotwires. The proposed method essentially removes the spatial averaging effect intrinsic to the cw lidar systems
A tropical West Pacific OH minimum and implications for stratospheric composition
Most of the short-lived biogenic and anthropogenic chemical species that are
emitted into the atmosphere break down efficiently by reaction with OH and do
not reach the stratosphere. Here we show the existence of a pronounced
minimum in the tropospheric column of ozone over the West Pacific, the main
source region for stratospheric air, and suggest a corresponding minimum of
the tropospheric column of OH. This has the potential to amplify the impact
of surface emissions on the stratospheric composition compared to the impact
when assuming globally uniform OH conditions. Specifically, the role of
emissions of biogenic halogenated species for the stratospheric halogen
budget and the role of increasing emissions of SO<sub>2</sub> in Southeast Asia or
from minor volcanic eruptions for the increasing stratospheric aerosol
loading need to be reassessed in light of these findings. This is also
important since climate change will further modify OH abundances and
emissions of halogenated species. Our study is based on ozone sonde
measurements carried out during the TransBrom cruise with the RV
<i>Sonne</i> roughly along 140–150° E in October 2009 and corroborating ozone and
OH measurements from satellites, aircraft campaigns and FTIR instruments.
Model calculations with the GEOS-Chem Chemistry and Transport Model (CTM) and
the ATLAS CTM are used to simulate the tropospheric OH distribution over the
West Pacific and the transport pathways to the stratosphere. The potential
effect of the OH minimum on species transported into the stratosphere is
shown via modeling the transport and chemistry of CH<sub>2</sub>Br<sub>2</sub> and SO<sub>2</sub>
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