On Aliasing Effects in the Contourlet Filter Bank

Publication in the conference proceedings of EUSIPCO, Florence, Italy, 200

High energy storage responses in all-oxide epitaxial relaxor ferroelectric thin films with the coexistence of relaxor and antiferroelectric-like behaviors

Relaxor ferroelectric Pb0.9La0.1(Zr0.52Ti0.48)O3 (PLZT) thin films have been epitaxially grown via pulsed laser deposition on SrRuO3/SrTiO3 single crystal with different orientations. The high recoverable energy-storage density and energy-storage efficiency in the epitaxial PLZT thin films are mainly caused by the coexistence of relaxor and antiferroelectric-like behaviors. The recoverable energy-storage density of 12.03, 12.51 and 12.74 J/cm3 and energy-storage efficiency of 86.50, 88.14 and 88.44%, respectively, for the PLZT(001), PLZT(011) and PLZT(111) thin films measured at 1000 kV/cm. The high energy density and high efficiency indicate that the relaxor epitaxial PLZT(111) thin film is a promising candidate for high pulsed power capacitors

Nouvelle stratégie antibiofilm par dépôt LBL d’un polyélectrolyte cationique sur la membrane de dialyse anionique AN69

Cette étude présente une stratégie antibiofilm appliquée à une membrane de dialyse, l’AN69; il s’agit de réaliser une modification initiale de la surface de la membrane par un polyélectrolyte cationique, le poly(diallyldiméthyl-ammonium), noté PDADMA, selon un protocole de type « layer-by-layer ». Les caractéristiques physico-chimiques des deux membranes, l’AN69 et l’AN69 modifiée par le PDADMA, sont suivies par la détermination de la modification de la charge de la membrane en mettant en oeuvre des mesures de potentiels d’écoulement et de nombres de transports de Li+, de perméabilité hydraulique et des analyses morphologiques et topographiques effectuées par les microscopies électroniques à balayage et à force atomique, respectivement avant et après exposition à E. coli et à un biofilm marin. Nos résultats montrent tout d’abord un rôle majeur joué par l’attraction électrostatique entre les microorganismes et l’AN69 modifiée par le PDADMA à l’origine d’une adhésion forte des bactéries.Par ailleurs, nous avons mis au point un protocole original d’élimination du biofilm marin. Ce protocole consiste à immerger la membrane modifiée par le PDADMA et encrassée, dans une solution de chlorure de sodium 2M afin d’écranter les charges électrostatiques à l’origine de l’accroche du polyélectrolyte et permettre le décrochage du PDADMA qui entraîne avec lui l’encrassement (constitué de bactéries et autres résidus de biofilm). La recharge d’un film frais de PDADMA permet alors une réutilisation à l’infini de la membrane AN69. La simplicité de ce protocole « de régénération » ouvre la possibilité d’une modification non permanente des membranes de dialyse, dans le but de limiter les problèmes récurrents de biocolmatage et d’augmenter les durées de vie des membranes en milieu marin.The harmful effects generated by biofilms have an extremely high cost. In this study, we were interested in the formation of marine biofilms forming on the wellknown anionic dialysis membrane AN69 used in the reduction of seawater salinity for the preparation of body-washing solutions. We focused our study on two membranes: AN69 and AN69 modified (denoted AN69 mod) by the sorption of poly(diallyldimethyl-ammonium), a cationic polyelectrolyte denoted by PDADMA. Physico-chemical characteristics (membrane charge from Li+ transport and streaming potential measurements, water flux from hydraulic permeability measurements and morphological/topographical measurements using SEM and AFM, respectively) were monitered during the exposure of both membranes to E. coli and natural marine biofouling solutions. Our results showed that the modification of the AN69 membrane by PDADMA its charge and increased its electrostatic affinity for bacteria. Electrostatics forces are, therefore, the main forces responsible for membrane biofouling. Furthermore we developed a simple antibiofilm protocol based on a one-step dipping operation applied to the fouled AN69 membrane which eliminates the PDADMA and associated bacteria. For the first time, all deposited marine bacteria were easily eliminated allowing for the regeneration and sustainable use of the AN69 membrane

Willingness to Pay for Improving Household Solid Waste Management in Vietnam

Management of solid waste is a major challenge in urban areas of most parts of the world, especially in developing countries. The study aimed to determine and estimate the willingness to pay (WTP) of the selected households for the improvement of solid waste management in Vietnam. The research evaluated WTP of household solid waste in case studies in Bien Hoa and My Tho cities using contingent valuation method (CVM). The data were collected through a closed-ended questionnaire survey and interviews with 200 households. The results showed that the most willingness to pay was equal to 10,000 and 15,000 VND per month. The respondents were willing to pay in Bien Hoa and My Tho with an average of 14,450 VND (0.63 USD) and 13,000 VND (0.56 USD) per month, respectively. Regression model identified influential factors on WTP of households in the two cities of Vietnam. The factors that significantly influence households’ WTP were monthly household income, education of respondents, age, occupation and solid waste volume (p<0.05). The results of this study can be used for the urban planning and implemented the sustainable development process in Bien Hoa and My Tho cities

Root rot pathogens of Cinnamomum cassia in Vietnam

A study was conducted to determine the pathogens causing root rot, wilt and dieback disease of Cinnamomum cassia (Chinese cinnamon or cassia) in Vietnam, in nurseries and plantations in the Yen Bai, Quang Ninh, Thanh Hoa and Quang Nam provinces, and streams in the Yen Bai province. Pathogens were identified using morphology and internal transcribed spacer (ITS) sequence analysis. The 204 isolates obtained included 125 Phytophthora isolates and 79 from other oomycete genera. There were 112 isolates of P. cinnamomi, four P. heveae, two P. virginiana, three P. multibullata and four P. × vanyenensis. The pathogenicity and virulence of 16 P. cinnamomi, two P. heveae, two P. multibullata and four P. × vanyenensis isolates were assessed using lesion size after under-bark inoculation of C. cassia stems, and root damage following inoculation of 4-month-old C. cassia seedlings. The most virulent isolate from both assessments was a P. cinnamomi from the Quang Nam plantation. Isolates of P. cinnamomi showed a wide range of virulence, with isolates from healthy trees or seedlings showing the lowest virulence. Isolates of P. × vanyenensis, P. multibullata and P. heveae showed moderate or low pathogenicity. This study showed that although P. cinnamomi is the most common pathogen associated with dieback disease in Vietnamese C. cassia plantations, other Phytophthora species may also cause this disease. Knowledge of the presence of these soil- and waterborne pathogens will encourage improved soil and water hygiene in nurseries and implement measures to prevent the spread of the pathogens in plantations

Photoluminescence Quenching Probes Spin Conversion and Exciton Dynamics in Thermally Activated Delayed Fluorescence Materials

peer reviewe

Structures, Energies, and Bonding Analysis of Monoaurated Complexes with N-Heterocyclic Carbene and Analogues

In this work, we computationally investigated from quantum chemical calculations (DFT) at the BP86 level with the various basis sets def2-SVP, def2-TZVPP, and TZ2P+, chemical bonding issues of the recently described carbene-analogues gold(I) complexes AuCl-NHEMe (Au1-NHE) with E = C – Pb. The optimized structures and the metal-ligand bond dissociation energy (BDE) were calculated, and the nature of the E→Au bond was studied with charge and energy decomposition methods. The equilibrium structures of the system showed that there were major differences in the bonded orientation from the ligands NHC-NHPb to gold(I) complex between the lighter and the heavier homologues. The BDEs results showed that the metal-carbene analogues bonds were very strong bonds and the strongest bond was calculated for Au1-NHC which had the bond strength De = 79.2 kcal/mol. Bonding analysis of Au1-NHE showed that NHE ligands exhibited donor-acceptor bonds with the σ lone pair electrons of NHE donated into the vacant orbital of the acceptor fragment (AuCl). The EDA-NOCV results indicated that the ligand NHE in Au1-NHE complexes were strong σ-donors and very weak π donor and the bond order in complexes was Au1-NHC > Au1-NHSi > Au1-NHGe > Au1-NHSn > Au1-NHPb. We also realised that the gold-ligand bond was characterized by a π back-donation component from the Au to the ligand. All investigated complexes in this study were suitable targets for synthesis and gave a challenge in designing Au nano-crystals of narrow size distribution from gold(I) complexes that carried versatile N-heterocyclic carbene-analogues NHE

Rapid hepatic clearance of full length CCN-2/CTGF: a putative role for LRP1-mediated endocytosis

CCN-2 (connective tissue growth factor; CTGF) is a key factor in fibrosis. Plasma CCN-2 has biomarker potential in numerous fibrotic disorders, but it is unknown which pathophysiological factors determine plasma CCN-2 levels. The proteolytic amino-terminal fragment of CCN-2 is primarily eliminated by the kidney. Here, we investigated elimination and distribution profiles of full length CCN-2 by intravenous administration of recombinant CCN-2 to rodents. After bolus injection in mice, we observed a large initial distribution volume (454 mL/kg) and a fast initial clearance (120 mL/kg/min). Immunosorbent assay and immunostaining showed that CCN-2 distributed mainly to the liver and was taken up by hepatocytes. Steady state clearance in rats, determined by continuous infusion of CCN-2, was fast (45 mL/kg/min). Renal CCN-2 clearance, determined by arterial and renal vein sampling, accounted for only 12 % of total clearance. Co-infusion of CCN-2 with receptor-associated protein (RAP), an antagonist of LDL-receptor family proteins, showed that RAP prolonged CCN-2 half-life and completely prevented CCN-2 internalization by hepatocytes. This suggests that hepatic uptake of CCN-2 is mediated by a RAP-sensitive mechanism most likely involving LRP1, a member of the LDL-receptor family involved in hepatic clearance of various plasma proteins. Surface plasmon resonance binding studies confirmed that CCN-2 is an LRP1 ligand. Co-infusion of CCN-2 with an excess of the heparan sulphate-binding protamine lowered the large initial distribution volume of CCN-2 by 88 % and reduced interstitial staining of CCN-2, suggesting binding of CCN-2 to heparan sulphate proteoglycans (HSPGs). Protamine did not affect clearance rate, indicating that RAP-sensitive clearance of CCN-2 is HSPG independent. In conclusion, unlike its amino-terminal fragment which is cleared by the kidney, fu

New neurons use Slit-Robo signaling to migrate through the glial meshwork and approach a lesion for functional regeneration

After brain injury, neural stem cell–derived neuronal precursors (neuroblasts) in the ventricular-subventricular zone migrate toward the lesion. However, the ability of the mammalian brain to regenerate neuronal circuits for functional recovery is quite limited. Here, using a mouse model for ischemic stroke, we show that neuroblast mi-gration is restricted by reactive astrocytes in and around the lesion. To migrate, the neuroblasts use Slit1-Robo2 signaling to disrupt the actin cytoskeleton in reactive astrocytes at the site of contact. Slit1-overexpressing neu-roblasts transplanted into the poststroke brain migrated closer to the lesion than did control neuroblasts. These neuroblasts matured into striatal neurons and efficiently regenerated neuronal circuits, resulting in functional recovery in the poststroke mice. These results suggest that the positioning of new neurons will be critical for func-tional neuronal regeneration in stem/progenitor cell–based therapies for brain injury