Was 14C über Sonne und Erde verrät

Das radioaktive Kohlenstoffisotop 14C, auch Radiokarbon genannt, ist ein wichtiger Informationsträger für die Geowissenschaften. Es hilft, unser Verständnis von Klimaprozessen, der Sonne, des Geodynamos und des Kohlenstoffkreislaufs der vergangenen 55 000 Jahre zu verbessern. Moderne Messmethoden erlauben auch 14C-Messungen an Kleinstproben. Das verringert die Unsicherheiten in den aktuellen IntCal20-Alterskalibrationskurven. Dadurch zeigen sich klarere Strukturen in den Veränderungen im 14C-Gehalt der Atmosphäre und des oberflächennahen Meerwassers während der vergangenen 55 000 Jahre. Dieser Fortschritt ermöglicht eine verbesserte Datierung und Untersuchungen von Sonnenaktivität, Erdmagnetfeld und Kohlenstoffkreislauf. In allen diesen Gebieten der Erdsystemforschung kommen Radiokarbon-Messungen erfolgreich zum Einsatz

Biases in radiocarbon dating of organic fractions in sediments from meromictic and seasonally hypoxic lakes

We present here radiocarbon dating results from two boreal lakes in Finland, which are permanently (meromictic) or seasonally stratified and contain continuous sequences of annually laminated sediments that started to form in the early Holocene. The radiocarbon dating results of different organic components were compared with the varve-based sediment chronologies. The deviation between the Lake Valkiajarvi varve chronology (8400 varve years 2-3% error estimate) and 33 C-14 dates taken from insoluble and soluble organic phases vary inconsistently throughout the Holocene. In extreme cases mean calibrated radiocarbon dates with 95.4% confidence levels (2 sigma) are -2350 and +2040 years offset when compared with the varve chronology. On average, the radiocarbon dates are offset by ca. +550 years. The deviation between the Lake Nautajarvi varve chronology (9898 varve years +/- 1% error estimate) and 26 C-14 dates analyzed with conventional and AMS methods indicates that radiocarbon dates are systematically older by 500-1300 years (about 900 years on average). This significant offset mean that radiocarbon dates obtained from organic bulk sediment of meromictic and seasonally hypoxic lakes must be cautiously interpreted because of the reservoir effect and carbon cycling at the sediment-water interface. Direct evidence was obtained from the dating of soluble fraction and insoluble organic matter from near bottom water in the monimolimnion of Lake Valkiajarvi, which yielded C-14 ages of 560 +/- 80 BP and 2070 +/- 140 BP, respectively. Our study reinforces previous results that age-depth models based on bulk sediment radiocarbon dates obtained on sediments of stratified lakes are of limited value for accurate dating of changes in land use and especially the commence of agriculture.Peer reviewe

A varved lake sediment record of ¹⁰Be solar activity proxy for the Lateglacial-Holocene transition

Solar modulated variations in cosmogenic radionuclide production provide both information on past changes in the activity of the Sun and a global synchronization tool. However, to date the use of cosmogenic radionuclides for these applications is almost exclusively based on 10Be records from ice cores and 14C time-series from tree rings, all including archive-specific limitations. We present the first 10Be record from annually laminated (varved) lake sediments for the Lateglacial-Holocene transition from Meerfelder Maar. We quantify environmental influences on the catchment and, consequently, 10Be deposition using a new approach based on regression analyses between our 10Be record and environmental proxy time-series from the same archive. Our analyses suggest that environmental influences contribute to up to 37% of the variability in our 10Be record, but cannot be the main explanation for major 10Be excursions. Corrected for these environmental influences, our 10Be record is interpreted to dominantly reflect changes in solar modulated cosmogenic radionuclide production. The preservation of a solar production signal in 10Be from varved lake sediments highlights the largely unexplored potential of these archives for solar activity reconstruction, as global synchronization tool and, thus, for more robust paleoclimate studies

Using an independent geochronology based on palaeomagnetic secular variation (PSV) and atmospheric Pb deposition to date Baltic Sea sediments and infer 14C reservoir age

Dating of sediment cores from the Baltic Sea has proven to be difficult due to uncertainties surrounding the C-14 reservoir age and a scarcity of macrofossils suitable for dating. Here we present the results of multiple dating methods carried out on cores in the Gotland Deep area of the Baltic Sea. Particular emphasis is placed on the Littorina stage (8 ka ago to the present) of the Baltic Sea and possible changes in the C-14 reservoir age of our dated samples. Three geochronological methods are used. Firstly, palaeomagnetic secular variations (PSV) are reconstructed, whereby ages are transferred to PSV features through comparison with varved lake sediment based PSV records. Secondly, lead (Pb) content and stable isotope analysis are used to identify past peaks in anthropogenic atmospheric Pb pollution. Lastly, C-14 determinations were carried out on benthic foraminifera (Elphidium spec.) samples from the brackish Littorina stage of the Baltic Sea. Determinations carried out on smaller samples (as low as 4 mu g C) employed an experimental, state-of-the-art method involving the direct measurement of CO2 from samples by a gas ion source without the need for a graphitisation step - the first time this method has been performed on foraminifera in an applied study. The PSV chronology, based on the uppermost Littorina stage sediments, produced ten age constraints between 6.29 and 1.29 cal ka BP, and the Pb depositional analysis produced two age constraints associated with the Medieval pollution peak. Analysis of PSV data shows that adequate directional data can be derived from both the present Littorina saline phase muds and Baltic Ice Lake stage varved glacial sediments. Ferrimagnetic iron sulphides, most likely authigenic greigite (Fe3S4), present in the intermediate Ancylus Lake freshwater stage sediments acquire a gyroremanent magnetisation during static alternating field (AF) demagnetisation, preventing the identification of a primary natural remanent magnetisation for these sediments. An inferred marine reservoir age offset (Delta R) is calculated by comparing the foraminifera C-14 determinations to a PSV & Pb age model. This Delta R is found to trend towards younger values upwards in the core, possibly due to a gradual change in hydrographic conditions brought about by a reduction in marine water exchange from the open sea due to continued isostatic rebound. (C) 2012 Elsevier Ltd. All rights reserved

Solar activity of the past 100 years inferred from 10Be in ice cores – implications for long-term solar activity reconstructions

Differences between 10Be records from Greenland and Antarctica over the last 100 years have led to different conclusions about past changes in solar activity. The reasons for this disagreement remain unresolved. We analyze a seasonally resolved 10Be record from a firn core (NEEM ice core project) in Northwestern Greenland for 1887-2002. By comparing the NEEM data to 10Be data from the NGRIP and Dye3 ice cores, we find that the Dye3 data after 1958 are significantly lower. These low values lead to a normalization problem in solar reconstructions when connecting 10Be variations to modern observations. Excluding these data strongly reduces the differences between solar reconstructions over the last 2000 years based on Greenland and Antarctic 10Be data. Furthermore, 10Be records from polar regions and group sunspot numbers do not support a substantial increase in solar activity for the 1937-1950 period as proposed by previous extensions of the neutron monitor data.This article is protected by copyright. All rights reserved

A geomagnetic estimate of heliospheric modulation potential over the last 175 years

Galactic cosmic rays (GCRs) interact with the Earth’s atmosphere to produce energetic neutrons and cosmogenic radionuclides, such as 14C. The atmosphere is partially shielded from the interstellar GCR spectrum by both the geomagnetic and solar magnetic fields. Solar shielding is often expressed as the heliospheric modulation potential , which consolidates information about the strength and structure of the solar magnetic field into a single parameter. For the period 1951 to today, can be estimated from ground-based neutron monitor data. Prior to 1950, 14C in tree rings can be used to estimate and hence the solar magnetic field, back centuries or millennia. Bridging the gap in the record is therefore of vital importance for long-term solar reconstructions. One method is to model using the sunspot number (SN) record. However, the SN record is only an indirect measure of the Sun’s magnetic field, introducing uncertainty, and the record suffers from calibration issues. Here we present a new reconstruction of based on geomagnetic data, which spans both the entire duration of the neutron monitor record and stretches back to 1845, providing a significant overlap with the 14C data. We first modify and test the existing model of based on a number of heliospheric parameters, namely the open solar flux , the heliospheric current sheet tilt angle , and the global heliospheric magnetic polarity . This modified model is applied to recently updated geomagnetic estimates of and cyclic variations of and . This approach is shown to produce an annual estimate of in excellent agreement with that obtained from neutron monitors over 1951 – 2023. It also suggests that ionisation chamber estimates of – which have previously been used to extend the instrumental estimate back from 1951 to 1933 – are not well calibrated. Comparison of the new geomagnetic with 14C estimates of suggests that the long-term trend is overestimated in the most recent 14C data, possibly due to hemispheric differences in the Suess effect, related to the release of carbon by the burning of fossil fuels. We suggest that the new geomagnetic estimate of will provide an improved basis for future calibration of long-term solar activity reconstructions

A Single-Year Cosmic Ray Event at 5410 BCE Registered in C-14 of Tree Rings

The annual C-14 data in tree rings is an outstanding proxy for uncovering extreme solar energetic particle (SEP) events in the past. Signatures of extreme SEP events have been reported in 774/775 CE, 992/993 CE, and similar to 660 BCE. Here, we report another rapid increase of C-14 concentration in tree rings from California, Switzerland, and Finland around 5410 BCE. These C-14 data series show a significant increase of similar to 6 parts per thousand in 5411-5410 BCE. The signature of C-14 variation is very similar to the confirmed three SEP events and points to an extreme short-term flux of cosmic ray radiation into the atmosphere. The rapid C-14 increase in 5411/5410 BCE rings occurred during a period of high solar activity and 60 years after a grand C-14 excursion during 5481-5471 BCE. The similarity of our C-14 data to previous events suggests that the origin of the 5410 BCE event is an extreme SEP event.Peer reviewe