2,247 research outputs found
A Highly Asymmetric Disc-like Mesogen Based on the Tetrabenzotriazaporphyrin Macrocyclic Ring System
Programming Protocol-Independent Packet Processors
P4 is a high-level language for programming protocol-independent packet
processors. P4 works in conjunction with SDN control protocols like OpenFlow.
In its current form, OpenFlow explicitly specifies protocol headers on which it
operates. This set has grown from 12 to 41 fields in a few years, increasing
the complexity of the specification while still not providing the flexibility
to add new headers. In this paper we propose P4 as a strawman proposal for how
OpenFlow should evolve in the future. We have three goals: (1)
Reconfigurability in the field: Programmers should be able to change the way
switches process packets once they are deployed. (2) Protocol independence:
Switches should not be tied to any specific network protocols. (3) Target
independence: Programmers should be able to describe packet-processing
functionality independently of the specifics of the underlying hardware. As an
example, we describe how to use P4 to configure a switch to add a new
hierarchical label
Atomically precise lateral modulation of a two-dimensional electron liquid in anatase TiO2 thin films
Engineering the electronic band structure of two-dimensional electron liquids
(2DELs) confined at the surface or interface of transition metal oxides is key
to unlocking their full potential. Here we describe a new approach to tailoring
the electronic structure of an oxide surface 2DEL demonstrating the lateral
modulation of electronic states with atomic scale precision on an unprecedented
length scale comparable to the Fermi wavelength. To this end, we use pulsed
laser deposition to grow anatase TiO2 films terminated by a (1 x 4) in-plane
surface reconstruction. Employing photo-stimulated chemical surface doping we
induce 2DELs with tunable carrier densities that are confined within a few TiO2
layers below the surface. Subsequent in-situ angle resolved photoemission
experiments demonstrate that the (1 x 4) surface reconstruction provides a
periodic lateral perturbation of the electron liquid. This causes strong
backfolding of the electronic bands, opening of unidirectional gaps and a
saddle point singularity in the density of states near the chemical potential
Recommended from our members
Responding to Climate Change: The Economy and Economics - Part of the Problem and Solution
The Climate Change Starter’s Guide provides an introduction and overview for education planners and practitioners on the wide range of issues relating to climate change and climate change education, including causes, impacts, mitigation and adaptation strategies, as well as some broad political and economic principles.
The aim of this guide is to serve as a starting point for mainstreaming climate change education into school curricula. It has been created to enable education planners and practitioners to understand the issues at hand, to review and analyse their relevance to particular national and local contexts, and to facilitate the development of education policies, curricula, programmes and lesson plans.
The guide covers four major thematic areas:
1. the science of climate change, which explains the causes and observed changes;
2. the social and human aspects of climate change including gender, health, migration, poverty and ethics;
3. policy responses to climate change including measures for mitigation and adaptation; and
4. education approaches including education for sustainable development, disaster reduction and sustainable lifestyles.
A selection of key resources in the form of publication titles or websites for further reading is provided after each of the thematic sections
Modeling the interactions of phthalocyanines in water: From the Cu(II)-tetrasulphonate to the metal-free phthalocyanine
A quantum and statistical study on the effects of the ions Cu2+ and SO3− in the solvent structure around the metal-free phthalocyanine (H2Pc) is presented. We developed an ab initio interaction potential for the system CuPc–H2O based on quantum chemical calculations and studied its
transferability to the H2Pc–H2O and [CuPc(SO3)4]4−–H2O interactions. The use of the molecular dynamics technique allows the determination of energetic and structural properties of CuPc, H2Pc, and [CuPc(SO3)4]4− in water and the understanding of the keys for the different behaviors of the three phthalocyanine (Pc) derivatives in water. The inclusion of the Cu2+ cation in the Pc structure reinforces the appearance of two axial water molecules and second-shell water molecules in the solvent structure, whereas the presence of SO3− anions implies a well defined hydration shell
of about eight water molecules around them making the macrocycle soluble in water. Debye– Waller factors for axial water molecules have been obtained in order to examine the potential sensitivity of the extended x-ray absorption fine structure technique to detect the axial water molecules.Ministerio de Ciencia e Innovación de España-CTQ2008-0527
Theoretical study on the hydrophobic and hydrophilic hydration on large solutes: The case of phthalocyanines in water
A theoretical study on the hydration phenomena of three representative Phthalocyanines (Pcs): the metal-free, H2Pc, and the metal-containing, Cu-phthalocyanine, CuPc, and its soluble sulphonated derivative, [CuPc(SO3)4]4−, is presented. Structural and dynamic properties of molecular dynamics trajectories of these Pcs in solution were evaluated. The hydration shells of the Pcs were defined by means of spheroids adapted to the solute shape. Structural analysis of the axial region compared to the peripheral region indicates that there are no significant changes among the different macrocycles, but that of [CuPc(SO3)4]4−, where the polyoxoanion presence induces a typically hydrophilic hydration structure. The analyzed water dynamic properties cover mean residence times, translational and
orientational diffusion coefficients, and hydrogen bond network. These properties allow a thorough discussion about the simultaneous existence of hydrophobic and hydrophilic hydration in these macrocycles, and indicate the trend of water structure to well define shells in the environment of hydrophobic solutes. The comparison between the structural and dynamical analysis of the hydration of the amphipathic [CuPc(SO3)4]4− and the non-soluble Cu–Pc shows a very weak coupling among the hydrophilic and hydrophobic fragments of the macrocycle. Quantitative results are employed to revisit the iceberg model proposed by Frank and Evans, leading to conclude that structure and dy- namics support a non-strict interpretation of the iceberg view, although the qualitative trends pointed out by the model are supported.Junta de AndalucÃa P11-FQM7607Ministerio de Ciencia e Innovación CTQ2008-0527
Standard Neutrino Spectrum from B-8 Decay
We present a systematic evaluation of the shape of the neutrino energy
spectrum produced by beta-decay of B. We place special emphasis on
determining the range of uncertainties permitted by existing laboratory data
and theoretical ingredients (such as forbidden and radiative corrections). We
review and compare the available experimental data on the
BBe decay chain. We analyze the theoretical and
experimental uncertainties quantitatively. We give a numerical representation
of the best-fit (standard-model) neutrino spectrum, as well as two extreme
deviations from the standard spectrum that represent the total (experimental
and theoretical) effective deviations. Solar neutrino experiments
that are currently being developed will be able to measure the shape of the
B neutrino spectrum above about 5 MeV. An observed distortion of the B
solar neutrino spectrum outside the range given in the present work could be
considered as evidence, at an effective significance level greater than three
standard deviations, for physics beyond the standard electroweak model. We use
the most recent available experimental data on the Gamow--Teller strengths in
the system to calculate the B neutrino absorption cross section on
chlorine: ~cm (
errors). The chlorine cross section is also given as a function of the neutrino
energy. The B neutrino absorption cross section in gallium is cm ( errors).Comment: Revised version, to appear in Phys. Rev.
Measurement of the Proton's Neutral Weak Magnetic Form Factor
We report the first measurement of the parity-violating asymmetry in elastic
electron scattering from the proton. The asymmetry depends on the neutral weak
magnetic form factor of the proton which contains new information on the
contribution of strange quark-antiquark pairs to the magnetic moment of the
proton. We obtain the value n.m. at
(GeV/c).Comment: 4 pages TEX, text available at
http://www.krl.caltech.edu/preprints/OAP.htm
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