15,928 research outputs found
Laboratory mid-IR spectra of equilibrated and igneous meteorites. Searching for observables of planetesimal debris
Meteorites contain minerals from Solar System asteroids with different
properties (like size, presence of water, core formation). We provide new
mid-IR transmission spectra of powdered meteorites to obtain templates of how
mid-IR spectra of asteroidal debris would look like. This is essential for
interpreting mid-IR spectra of past and future space observatories, like the
James Webb Space Telescope. We show that the transmission spectra of wet and
dry chondrites, carbonaceous and ordinary chondrites and achondrite and
chondrite meteorites are distinctly different in a way one can distinguish in
astronomical mid-IR spectra. The two observables that spectroscopically
separate the different meteorites groups (and thus the different types of
parent bodies) are the pyroxene-olivine feature strength ratio and the peak
shift of the olivine spectral features due to an increase in the iron
concentration of the olivine
Towards a Soil Information System with quantified accuracy : a prototype for mapping continuous soil properties
This report describes the potential and functionality of software for spatial analysis, prediction and stochastic simulation of continuous soil properties using data from the Dutch Soil Information System (BIS). A geostatistical framework and R codes were developed. The geostatistical model of a soil property has a deterministic component representing the mean value within a soil category, and a stochastic component of standardized residuals. The standardized residuals are interpolated or simulated based on the simple kriging system. The software was tested in four case studies: exchangeable soil pH, clay content, organic matter content and Mean Spring Water table depth (MSW). It is concluded that the geostatistical framework and R codes developed in this study enable to predict values of continuous soil properties spatially, and to quantify the inaccuracy of these predictions. The inaccuracy of a spatial prediction at a certain location is quantified by the kriging variance, which can be interpreted as an indication of the uncertainty about the true value
Evidence for precession of the isolated neutron star RX J0720.4-3125
The XMM-Newton spectra of the isolated neutron star RX J0720.4-3125 obtained
over 4.5 years can be described by sinusoidal variations in the inferred
blackbody temperature, the size of the emitting area and the depth of the
absorption line with a period of 7.1 +/- 0.5 years, which we suggest to be the
precession period of the neutron star. Precession of a neutron star with two
hot spots of different temperature and size, probably not located exactly in
antipodal positions, may account for the variations in the X-ray spectra,
changes in the pulsed fraction, shape of the light curve and the phase-lag
between soft and hard energy bands observed from RX J0720.4-3125. An
independent sinusoidal fit to published and new pulse timing residuals from a
coherent analysis covering ~12 years yields a consistent period of 7.7 +/- 0.6
years supporting the precession model.Comment: Accepted for publication in A&A Letters, 5 pages, 5 figure
Practical Aspects of Carbon-Carbon Cross-Coupling Reactions Using Heteroarenes
The use of cross-coupling reactions for the preparation of alkylated and arylated heteroaromatic compounds has increased tremendously over the past two decades. This has been driven on the one hand by the increasingly complex structures of new drugs, most of which contain one or more heterocyclic motifs. On the other hand, the development of new catalysts and reaction conditions for these reactions has rendered even the most unreactive of heteroarenes amenable to cross-coupling chemistry. Not only have new bulky electron-donating ligands been created that allow the coupling of aryl chlorides under mild conditions, but also the use of ligand-free palladium, in particular at very low doses, sometimes called homeopathic palladium, has served to bring down the cost of these reactions. More recent and enabling developments are the use of catalysts based on cheap metals such as nickel, copper, and iron. Scale-up issues are availability and cost of starting materials, cost of the catalysts (related to cost of the metal and the ligand, intrinsic activity and stability of the catalyst), solvent choice, and removal of the metal t
Scaling of polymers in aligned rods
We study the behavior of self avoiding polymers in a background of vertically
aligned rods that are either frozen into random positions or free to move
horizontally. We find that in both cases the polymer chains are highly
elongated, with vertical and horizontal size exponents that differ by a factor
of 3. Though these results are different than previous predictions, our results
are confirmed by detailed computer simulations.Comment: 4 pages, 4 figure
Location and sizes of forsterite grains in protoplanetary disks: interpretation from the Herschel DIGIT programme
The spectra of protoplanetary disks contain mid- and far- infrared emission
features produced by forsterite dust grains. The spectral features contain
information about the forsterite temperature, chemical composition and grain
size. We aim to characterize how the 23 and 69 micron features can be used to
constrain the physical locations of forsterite in disks. We check for
consistency between two independent forsterite temperature measurements: the
23/69 feature strength ratio and the shape of the 69 micron band. We performed
radiative transfer modeling to study the effect of disk properties to the
forsterite spectral features. Temperature-dependent forsterite opacities were
considered in self-consistent models to compute forsterite emission from
protoplanetary disks. Modelling grids are presented to study the effects of
grain size, disk gaps, radial mixing and optical depth to the forsterite
features. Independent temperature estimates derived from the 23/69 feature
strength ratio and the 69 micron band shape are most inconsistent for HD141569
and Oph IRS 48. A case study of the disk of HD141569 shows two solutions to fit
the forsterite spectrum. A model with T ~ 40 K, iron-rich (~0-1 % Fe) and 1
micron forsterite grains, and a model with warmer (T ~ 100 K), iron-free, and
larger (10 micron) grains. We find that for disks with low upper limits of the
69 micron feature (most notably in flat, self-shadowed disks), the forsterite
must be hot, and thus close to the star. We find no correlation between disk
gaps and the presence or absence of forsterite features. We argue that the 69
micron feature of the evolved transitional disks HD141569 and Oph IRS 48 is
most likely a tracer of larger (i.e. ~10 micron) forsterite grains.Comment: Accepted for publication in A&A. 14 pages, 9 figure
17O NMR study of the intrinsic magnetic susceptibility and spin dynamics of the quantum kagome antiferromagnet ZnCu3(OH)6Cl2
We report through 17O NMR, an unambiguous local determination of the
intrinsic kagome lattice spin susceptibility as well as that created around
non-magnetic defects issued from natural Zn/ Cu exchange in the S=1/2 (Cu2+)
herbertsmithite ZnCu3(OH)6Cl2 compound. The issue of a singlet-triplet gap is
addressed. The magnetic response around a defect is found to markedly differ
from that observed in non-frustrated antiferromagnetic materials. Finally, we
discuss our relaxation measurements in the light of Cu and Cl NMR data
[cond-mat 070314] and suggest a flat q-dependence of the excitations.Comment: Accepted for publication in Phys. Rev. Lett., 3 jan. 2008 Figure 1
has been modified to include a two-components fit of the 17O NMR spectru
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