People from Brač, emigrant press in Chile and newspaper Domovina - from the late 19th century to the beginning of World War I

Cilj je rada postaviti ishodišta za proučavanje povijesti hrvatskog iseljeničkog novinstva u Čileu od najranijeg razdoblja doseljenja Hrvata do kraja 1914. godine, među kojima je brojčano dominantnu grupaciju činilo stanovništvo s Brača. Radilo se prvenstveno o ekonomskoj migraciji uzrokovanoj ekonomskim promjenama u društvu općenito, ali i ekonomskim promjenama kao posljedicama političkih kretanja. U novu domovinu donose tradicionalnu potrebu organiziranja u razna društva, ali i svijest o vlastitoj nacionalnoj pripadnosti s vlastitim jezikom. Neobično brza asimilacija (već u prvoj generaciji) dovodi u pitanje opstojnost te potrebu očuvanja baštine. Iseljeničke novine u kojima surađuju, uređuju ih i pokreću Bračani – novinari, među kojima se ističu Ivan Krstulović i Luka Bonačić s novinama „Domovina“ iz Punta Arenasa, u dosadašnjoj literaturi sagledavane su gotovo isključivo s aspekta političke orijentacije i borbe. Cilj je rada kroz primjer rubrike „Iz mjesta i okolice“, koja je održala kontinuitet tijekom cijelog razdoblja izlaženja lista „Domovina“ i čijim je sastavnim dijelom bila, prikazati, s aspekta socijalne povijesti, da su lokalne novine odražavale i bilježile pojave i događanja značajna za svakodnevni život zajednice sa svrhom očuvanja njezina identiteta.The topic of this paper is to set the starting point for studying the history of Croatian emigrant journalism in Chile from the earliest period of the settlement of Croats until the end of 1914, including the dominant population group from Brač. It was primarily the economic migration, which was caused by economic changes in the society in general, and economic changes as a consequence of political movements. The immigrants had the need for organizing themselves in various societies in the new country, and they also had the awareness of their own nationality and language. The unusually rapid assimilation (already in the first generation) calls into question the viability and the need to preserve heritage. Immigrant newspapers edited and run by Brač emigrant journalists, most notably Ivan Krstulović and Luka Bonačić, with the newspaper Domovina from Punta Arenas, were in the current literature perceived almost exclusively in terms of political orientation and struggle. The aim of this paper is to show that the local newspaper Domovina reflected and recorded phenomena and events significant for the daily life of the community with the intention of preservation its identity from the perspective of social history, especially in the section From the town and surrounding areas

La Malle à Gouffé, affaire Eyraud-Bompard / Maurice Mayen

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Ligand-Based Phase Control in Porous Molecular Assemblies

Functionalization of isophthalic acid ligands with linear alkoxide groups from ethoxy through pentoxy is shown to have a pronounced effect on both the synthesis of porous paddlewheel-based molecular assemblies and their resulting surface areas and gas adsorption properties. Shorter chain length is compatible with either tetragonal or hexagonal two-dimensional materials, with the hexagonal phase favored with longer chain length. Precise tuning of reaction conditions affords discrete molecular species that are soluble in a variety of organic solvents. The isolated porous molecules display BET surface areas ranging from 125 m²/g to 545 m²/g. The pentoxide-based molecular assembly shows considerable promise for the separation of hydrocarbons with average isosteric heats of adsorption of −48 and −31 kJ/mol for ethylene and ethane, respectively

Ligand-Based Phase Control in Porous Molecular Assemblies

Functionalization of isophthalic acid ligands with linear alkoxide groups from ethoxy through pentoxy is shown to have a pronounced effect on both the synthesis of porous paddlewheel-based molecular assemblies and their resulting surface areas and gas adsorption properties. Shorter chain length is compatible with either tetragonal or hexagonal two-dimensional materials, with the hexagonal phase favored with longer chain length. Precise tuning of reaction conditions affords discrete molecular species that are soluble in a variety of organic solvents. The isolated porous molecules display BET surface areas ranging from 125 m²/g to 545 m²/g. The pentoxide-based molecular assembly shows considerable promise for the separation of hydrocarbons with average isosteric heats of adsorption of −48 and −31 kJ/mol for ethylene and ethane, respectively

Selective Gas Adsorption in Highly Porous Chromium(II)-Based Metal–Organic Polyhedra

Selective Gas Adsorption in Highly Porous Chromium(II)-Based Metal–Organic Polyhedr

Ligand-Based Phase Control in Porous Molecular Assemblies

Functionalization of isophthalic acid ligands with linear alkoxide groups from ethoxy through pentoxy is shown to have a pronounced effect on both the synthesis of porous paddlewheel-based molecular assemblies and their resulting surface areas and gas adsorption properties. Shorter chain length is compatible with either tetragonal or hexagonal two-dimensional materials, with the hexagonal phase favored with longer chain length. Precise tuning of reaction conditions affords discrete molecular species that are soluble in a variety of organic solvents. The isolated porous molecules display BET surface areas ranging from 125 m²/g to 545 m²/g. The pentoxide-based molecular assembly shows considerable promise for the separation of hydrocarbons with average isosteric heats of adsorption of −48 and −31 kJ/mol for ethylene and ethane, respectively

Ligand-Based Phase Control in Porous Molecular Assemblies

Functionalization of isophthalic acid ligands with linear alkoxide groups from ethoxy through pentoxy is shown to have a pronounced effect on both the synthesis of porous paddlewheel-based molecular assemblies and their resulting surface areas and gas adsorption properties. Shorter chain length is compatible with either tetragonal or hexagonal two-dimensional materials, with the hexagonal phase favored with longer chain length. Precise tuning of reaction conditions affords discrete molecular species that are soluble in a variety of organic solvents. The isolated porous molecules display BET surface areas ranging from 125 m²/g to 545 m²/g. The pentoxide-based molecular assembly shows considerable promise for the separation of hydrocarbons with average isosteric heats of adsorption of −48 and −31 kJ/mol for ethylene and ethane, respectively

Ligand-Based Phase Control in Porous Molecular Assemblies

Functionalization of isophthalic acid ligands with linear alkoxide groups from ethoxy through pentoxy is shown to have a pronounced effect on both the synthesis of porous paddlewheel-based molecular assemblies and their resulting surface areas and gas adsorption properties. Shorter chain length is compatible with either tetragonal or hexagonal two-dimensional materials, with the hexagonal phase favored with longer chain length. Precise tuning of reaction conditions affords discrete molecular species that are soluble in a variety of organic solvents. The isolated porous molecules display BET surface areas ranging from 125 m²/g to 545 m²/g. The pentoxide-based molecular assembly shows considerable promise for the separation of hydrocarbons with average isosteric heats of adsorption of −48 and −31 kJ/mol for ethylene and ethane, respectively

Ligand-Based Phase Control in Porous Molecular Assemblies

Functionalization of isophthalic acid ligands with linear alkoxide groups from ethoxy through pentoxy is shown to have a pronounced effect on both the synthesis of porous paddlewheel-based molecular assemblies and their resulting surface areas and gas adsorption properties. Shorter chain length is compatible with either tetragonal or hexagonal two-dimensional materials, with the hexagonal phase favored with longer chain length. Precise tuning of reaction conditions affords discrete molecular species that are soluble in a variety of organic solvents. The isolated porous molecules display BET surface areas ranging from 125 m²/g to 545 m²/g. The pentoxide-based molecular assembly shows considerable promise for the separation of hydrocarbons with average isosteric heats of adsorption of −48 and −31 kJ/mol for ethylene and ethane, respectively

Design and Synthesis of Porous Nickel(II) and Cobalt(II) Cages

Coordination assemblies containing transition-metal cations with coordinatively unsaturated sites remain a challenging target in the synthesis of porous molecules. Herein, we report the design, synthesis, and characterization of three porous hybrid inorganic/organic porous molecular assemblies based on cobalt­(II) and nickel­(II). Precise tuning of ligand functionalization allows for the isolation of molecular species in addition to two- and three-dimensional metal–organic frameworks. The cobaltous and nickelous cage compounds display excellent thermal stabilities in excess of 473 K and Brunauer–Emmett–Teller surface areas on the order of 200 m²/g. The precise ligand functionalization utilized here to control phases between discrete molecules and higher-dimensional solids can potentially further be tuned to optimize the porosity and solubility in future molecular systems