Toward a better understanding of the mid-infrared emission in the LMC

In this paper we aim to constrain for the first time the dust emission in the mid-to-far infrared domain, in the LMC, with the use of the Spitzer IRS and MIPS SED data, combined with Herschel data. We also consider UV extinction predictions derived from modeling. We selected 10 regions observed as part of the SAGE-Spec program, to probe dust properties in various environments (diffuse, molecular and ionized regions). All data were smoothed to the 40arcsec angular resolution. The SEDs were modeled with DustEM models, using the standard Mathis RF, as well as three additional RFs, with stellar clusters ages ranging from 4 Myr to 600 Myr. Standard dust models used to reproduce the Galactic diffuse medium are clearly not able to reproduce the dust emission in the MIR wavelength domain. This analysis evidences the need of adjusting parameters describing the dust size distribution and shows a clear distinct behavior according to the type of environments. In addition, whereas the small grain emission always seems to be negligible at long wavelengths in our Galaxy, the contribution of this small dust component could be more important than expected, in the submm-mm range, in the LMC averaged SED. Properties of the small dust component of the LMC are clearly different from those of our Galaxy. Its abundance, significantly enhanced, could be the result of large grains shattering due to strong shocks or turbulence. In addition, this grain component in the LMC systematically shows smaller grain size in the ionized regions compared to the diffuse medium. Predictions of extinction curves show significantly distinct behaviors depending on the dust models but also from one region to another. Comparison of model predictions with the LMC mean extinction curve shows that no model gives satisfactory agreement using the Mathis radiation field while using a harder radiation field tends to improve the agreementComment: Accepted for publication in A&

Atomic clusters of magnetic oxides: Structure and phonons

This work represents a combined experimental and theoretical study of structural and magnetic properties of clusters made of cobalt, chromium, and manganese oxides. The clusters were prepared in a molecular cluster source by oxidation of laser-vaporized metal and studied in a time-of-flight spectrometer. Infrared laser-induced cluster dissociation experiments revealed the spectrum of cluster vibrational states. We also performed ab initio local spin density approximation calculations of the equilibrium geometry, electronic structure, and magnetic properties of these clusters

Modeling and predicting the shape of the far-infrared to submillimeter emission in ultra-compact HII regions and cold clumps

Dust properties are very likely affected by the environment in which dust grains evolve. For instance, some analyses of cold clumps (7 K- 17 K) indicate that the aggregation process is favored in dense environments. However, studying warm (30 K-40 K) dust emission at long wavelength ($\lambda$$>$300 $\mu$m) has been limited because it is difficult to combine far infared-to-millimeter (FIR-to-mm) spectral coverage and high angular resolution for observations of warm dust grains. Using Herschel data from 70 to 500 $\mu$m, which are part of the Herschel infrared Galactic (Hi-GAL) survey combined with 1.1 mm data from the Bolocam Galactic Plane Survey (BGPS), we compared emission in two types of environments: ultra-compact HII (UCHII) regions, and cold molecular clumps (denoted as cold clumps). With this comparison we tested dust emission models in the FIR-to-mm domain that reproduce emission in the diffuse medium, in these two environments (UCHII regions and cold clumps). We also investigated their ability to predict the dust emission in our Galaxy. We determined the emission spectra in twelve UCHII regions and twelve cold clumps, and derived the dust temperature (T) using the recent two-level system (TLS) model with three sets of parameters and the so-called T-$\beta$ (temperature-dust emissvity index) phenomenological models, with $\beta$ set to 1.5, 2 and 2.5. We tested the applicability of the TLS model in warm regions for the first time. This analysis indicates distinct trends in the dust emission between cold and warm environments that are visible through changes in the dust emissivity index. However, with the use of standard parameters, the TLS model is able to reproduce the spectral behavior observed in cold and warm regions, from the change of the dust temperature alone, whereas a T-$\beta$ model requires $\beta$ to be known.Comment: Accepted for publication in A&A. 19 pages, 8 figures, 7 table

Disks around Hot Stars in the Trifid Nebula

We report on mid-IR observations of the central region in the Trifid nebula, carried out with ISOCAM in several broad-band infrared filters and in the low resolution spectroscopic mode provided by the circular variable filter. Analysis of the emission indicates the presence of a hot dust component (500 to 1000 K) and a warm dust component at lower temperatures (150-200 K) around several members of the cluster exciting the HII region, and other stars undetected at optical wavelengths. Complementary VLA observations suggest that the mid-IR emission could arise from a dust cocoon or a circumstellar disk, evaporated under the ionization of the central source and the exciting star of the nebula. In several sources the $9.7\mu m$ silicate band is seen in emission. One young stellar source shows indications of crystalline silicates in the circumstellar dust.Comment: 4 pages with 1 figur

Ices in Star-Forming Regions: First Results from VLT-ISAAC

The first results from a VLT-ISAAC program on L- and M-band infrared spectroscopy of deeply-embedded young stellar objects are presented. The advent of 8-m class telescopes allows high S/N spectra of low-luminosity sources to be obtained. In our first observing run, low- and medium-resolution spectra have been measured toward a dozen objects, mostly in the Vela and Chamaeleon molecular clouds. The spectra show strong absorption of H2O and CO ice, as well as weak features at `3.47' and 4.62 mu. No significant solid CH3OH feature at 3.54 mu is found, indicating that the CH3OH/H2O ice abundance is lower than toward some massive protostars. Various evolutionary diagnostics are investigated for a set of sources in Vela.Comment: 8 pages, 4 figures, to appear in The Origins of Stars and Planets: the VLT View, eds. J. Alves, M. McCaughrean (Springer Verlag

Carbon dioxide-methanol intermolecular complexes in interstellar grain mantles

Wetensch. publicatieFaculteit der Wiskunde en Natuurwetenschappe

TIMASSS : The IRAS16293-2422 Millimeter And Submillimeter Spectral Survey: Tentative Detection of Deuterated Methyl Formate (DCOOCH3)

High deuterium fractionation is observed in various types of environment such as prestellar cores, hot cores and hot corinos. It has proven to be an efficient probe to study the physical and chemical conditions of these environments. The study of the deuteration of different molecules helps us to understand their formation. This is especially interesting for complex molecules such as methanol and bigger molecules for which it may allow to differentiate between gas-phase and solid-state formation pathways. Methanol exhibits a high deuterium fractionation in hot corinos. Since CH3OH is thought to be a precursor of methyl formate we expect that deuterated methyl formate is produced in such environments. We have searched for the singly-deuterated isotopologue of methyl formate, DCOOCH3, in IRAS 16293-2422, a hot corino well-known for its high degree of methanol deuteration. We have used the IRAM/JCMT unbiased spectral survey of IRAS 16293-2422 which allows us to search for the DCOOCH3 rotational transitions within the survey spectral range (80-280 GHz, 328-366 GHz). The expected emission of deuterated methyl formate is modelled at LTE and compared with the observations.} We have tentatively detected DCOOCH3 in the protostar IRAS 16293-2422. We assign eight lines detected in the IRAM survey to DCOOCH3. Three of these lines are affected by blending problems and one line is affected by calibration uncertainties, nevertheless the LTE emission model is compatible with the observations. A simple LTE modelling of the two cores in IRAS 16293-2422, based on a previous interferometric study of HCOOCH3, allows us to estimate the amount of DCOOCH3 in IRAS 16293-2422. Adopting an excitation temperature of 100 K and a source size of 2\arcsec and 1\farcs5 for the A and B cores, respectively, we find that N(A,DCOOCH3) = N(B,DCOOCH3) ~ 6.10^14 /cm2. The derived deuterium fractionation is ~ 15%, consistent with values for other deuterated species in this source and much greater than that expected from the deuterium cosmic abundance. DCOOCH3, if its tentative detection is confirmed, should now be considered in theoretical models that study complex molecule formation and their deuteration mechanisms. Experimental work is also needed to investigate the different chemical routes leading to the formation of deuterated methyl formate

Spectropolarimetry of the 3.4 micron absorption feature in NGC 1068

In order to test the silicate-core/organic-mantle model of galactic interstellar dust, we have performed spectropolarimetry of the 3.4 micron C-H bond stretch that is characteristic of aliphatic hydrocarbons, using the nucleus of the Seyfert 2 galaxy, NGC 1068, as a bright, dusty background source. Polarization calculations show that, if the grains in NGC 1068 had the properties assigned by the core-mantle model to dust in the galactic diffuse ISM, they would cause a detectable rise in polarization over the 3.4 micron feature. No such increase is observed. We discuss modifications to the basic core-mantle model, such as changes in grain size or the existence of additional non-hydrocarbon aligned grain populations, which could better fit the observational evidence. However, we emphasize that the absence of polarization over the 3.4 micron band in NGC 1068 - and, indeed, in every line of sight examined to date - can be readily explained by a population of small, unaligned carbonaceous grains with no physical connection to the silicates.Comment: ApJ, accepte

Deuterated water in the solar-type protostars NGC 1333 IRAS 4A and IRAS 4B

Aims. The aim of this paper is to study deuterated water in the solar-type protostars NGC1333 IRAS4A and IRAS4B, to compare their HDO abundance distribution with other star-forming regions, and to constrain their HDO/H2O ratios. Methods. Using the Herschel/HIFI instrument as well as ground-based telescopes, we observed several HDO lines covering a large excitation range (Eup/k=22-168 K) towards these protostars and an outflow position. Non-LTE radiative transfer codes were then used to determine the HDO abundance profiles in these sources. Results. The HDO fundamental line profiles show a very broad component, tracing the molecular outflows, in addition to a narrower emission component and a narrow absorbing component. In the protostellar envelope of NGC1333 IRAS4A, the HDO inner (T>100 K) and outer (T<100 K) abundances with respect to H2 are estimated at 7.5x10^{-9} and 1.2x10^{-11}, respectively, whereas, in NGC1333 IRAS4B, they are 1.0x10^{-8} and 1.2x10^{-10}, respectively. Similarly to the low-mass protostar IRAS16293-2422, an absorbing outer layer with an enhanced abundance of deuterated water is required to reproduce the absorbing components seen in the fundamental lines at 465 and 894 GHz in both sources. This water-rich layer is probably extended enough to encompass the two sources as well as parts of the outflows. In the outflows emanating from NGC1333 IRAS4A, the HDO column density is estimated at about (2-4)x10^{13} cm^{-2}, leading to an abundance of about (0.7-1.9)x10^{-9}. An HDO/H2O ratio between 7x10^{-4} and 9x10^{-2} is derived in the outflows. In the warm inner regions of these two sources, we estimate the HDO/H2O ratios at about 1x10^{-4}-4x10^{-3}. This ratio seems higher (a few %) in the cold envelope of IRAS4A, whose possible origin is discussed in relation to formation processes of HDO and H2O.Comment: 16 pages, 13 figure