Rubberised bitumen manufacturing assisted by rheological measurements

This paper investigates the effect of processing temperature and time on the rheological properties of recycled tyre rubber-modified bitumens (RTR-MBs) produced using two different base binders and an ambient ground crumb rubber modifier (CRM). The production of the RTR-MBs was accomplished by means of a standard Brookfield rotational viscometer together with a modified impeller, dual helical impeller, to allow mixing as well as real-time viscosity measurements of the produced RTR-MBs. The rheological properties of the final RTR-MBs were determined by means of standard dynamic mechanical analysis oscillatory and multiple stress creep recovery testing using a dynamic shear rheometer. The results indicate that the low processing conditions (160°C and 60 min) are not appropriate for developing RTR-MBs with enhanced physical and rheological properties. However, allowing the crumb rubber to interact with the base binder for longer mixing times (140 min) led to the development of an enhanced rubber (polymer) network structure within the blend (i.e. swelling of the CRM particles) and superior rheological properties. At the other extreme, using high-processing conditions (200°C and 140 min) led to RTR-MBs in which the rubber network had been subjected to devulcanisation and depolymerisation with a subsequent reduction in modification

Physical and rheological characterization of carbonated bitumen for paving applications

In the paving industry, current attempts aimed at reducing greenhouse gas emissions have focused on the development of technologies that decrease bitumen viscosity so that asphalt mixtures can be produced at temperatures that are lower than conventional mixing temperature for hot-mix asphalt. This study focuses on the feasibility of producing new lower energy asphalt mixtures using CO2-modified bitumen. Gravimetric sorption techniques were used to establish the kinetics of CO2 diffusion in bitumen at multiple pressures. The rheological properties of the carbonated bitumen were characterized at multiple temperatures and loading frequencies using a dynamic shear rheometer.The results showed that CO2, at concentrations of up to about 0.3% w/w, caused significant (up to 3-folds) reduction in bitumen viscosity. A 10-fold increase in equilibrium CO2 uptake was observed when binders were conditioned in CO2 at 300 psi versus at 40 psi. The carbonated bitumen developed in this study has potential application in the production of lower energy asphalt mixtures. The work presents a novel application of CO2 at subcritical conditions, to reducing bitumen viscosity so that asphalt can be produced at lower temperature for paving applications. The work represents the first time such as attempt has been in the asphalt paving industry

Thermo-rheological analysis of WMA-additive modified binders

Thermo-rheological characteristics of unmodified and modified bitumen have significant impacts on the mechanical response of asphalt. This study investigates the impacts of an organic and a chemical Warm Mix Asphalt additive on bitumen thermo-rheological and mechanical characteristics. Modified binders with different concentrations of each additive were studied and analysed comparatively to a 40/60 penetration grade bitumen. Frequency sweep tests were performed at different ageing levels to characterise the Linear Viscoelastic properties. The multiple stress creep and recovery, linear amplitude sweep (LAS) and low temperature creep stiffness tests, together with the Glover–Rowe (G–R) fatigue parameter (determined from fitting of the 2S2P1D model to the complex shear modulus and phase angle master curves) were used to analyse the performance of the binders at critical operating temperatures. The results demonstrated the necessity to analyse the behavior of the studied binders beyond the limits of linear viscoelasticity to better characterise these types of bitumen. The results also indicated that both additives retarded bitumen ageing with the organic additive increasing bitumen elastic response while the chemical additive increased its viscous response. The results also showed an excellent correlation between the G–R parameter and LAS results which suggests the ability to use this parameter in characterising fatigue performance of the studied binders. This also suggests that bitumen fatigue life may be improving over time due to the increased elastic behahviour during ageing so long as a certain critical level of ageing is not reached

Classical percolation fingerprints in the high-temperature regime of the integer quantum Hall effect

We have performed magnetotransport experiments in the high-temperature regime (up to 50 K) of the integer quantum Hall effect for two-dimensional electron gases in semiconducting heterostructures. While the magnetic field dependence of the classical Hall law presents no anomaly at high temperatures, we find a breakdown of the Drude-Lorentz law for the longitudinal conductance beyond a crossover magnetic field B_c ~ 1 T, which turns out to be correlated with the onset of the integer quantum Hall effect at low temperatures. We show that the high magnetic field regime at B > B_c can be understood in terms of classical percolative transport in a smooth disordered potential. From the temperature dependence of the peak longitudinal conductance, we extract scaling exponents which are in good agreement with the theoretically expected values. We also prove that inelastic scattering on phonons is responsible for dissipation in a wide temperature range going from 1 to 50 K at high magnetic fields.Comment: 14 pages + 8 Figure

Influence of the single-particle Zeeman energy on the quantum Hall ferromagnet at high filling factors

In a recent paper [B. A. Piot et al., Phys. Rev. B 72, 245325 (2005)], we have shown that the lifting of the electron spin degeneracy in the integer quantum Hall effect at high filling factors should be interpreted as a magnetic-field-induced Stoner transition. In this work, we extend the analysis to investigate the influence of the single-particle Zeeman energy on the quantum Hall ferromagnet at high filling factors. The single-particle Zeeman energy is tuned through the application of an additional in-plane magnetic field. Both the evolution of the spin polarization of the system and the critical magnetic field for spin splitting are well described as a function of the tilt angle of the sample in the magnetic field.Comment: Published in Phys. Rev.

Moisture susceptibility of high and low compaction dry process crumb rubber modified asphalt mixtures

The field performance of dry process crumb rubber-modified (CRM) asphalt mixtures has been reported to be inconsistent with stripping and premature cracking on the surfacing. One of the concerns is that, because achieving field compaction of CRM material is difficult due to the inherent resilient nature of the rubber particle, nonuniform field compaction may lead to a deficient bond between rubber and bitumen. To assess the influence of compaction, a series of CRM and control mixtures was produced and compacted at two levels: 4% (low, optimum laboratory compaction) and 8% (high, field experience) air void content. The long-term durability, in regard to moisture susceptibility of the mixtures, was assessed by conducting repeated moisture conditioning cycles. Mechanical properties (stiffness, fatigue, and resistance to permanent deformation) were determined in the Nottingham Asphalt Tester. Results indicated that compared with conventional mixtures, the CRM mixtures, regardless of compaction effort, are more susceptible to moisture with the degree of susceptibility primarily depending on the amount of rubber in the mixture, rather than the difference in compaction. This behavior is different from that of conventional mixtures in which, as expected, poorly compacted mixtures were found to be more susceptible to moisture than were well-compacted mixtures

Observation of reversible moisture damage in asphalt mixtures

Durability of asphalt mixtures conditioned in hot water was investigated using stiffness measurements. Stiffness generally decreased with conditioning time. The effect of moisture on stiffness was found to be reversible as moisture conditioned-asphalt mixtures that had lost up to 80% of their initial stiffness fully recovered upon subsequent drying. Estimates of mastic film thickness and length of diffusion paths obtained from image analysis of X-ray CT scans of the asphalt mixtures suggest moisture diffusion was mainly restricted to the bulk mastic. The results suggest cohesive rather than adhesive failure dominated the durability of asphalt mixtures under the long-term moisture exposure used in this study

Simulations of nanograting-assisted light coupling in GaN planar waveguide

The numerical simulations of nanogratings integrated with gallium nitride (GaN) planar waveguides as well as the experimental in-coupling results are presented. A simulation tool based on the eigenmode expansion method and advanced boundary conditions provided a rigorous model of 400-nm-period grating couplers. A full-vectorial Maxwell solver allowed performing a number of simulations with varying grating parameters, where coupling efficiency, reflection and transmission characteristics of device were calculated. Gratings with different etch depths and arbitrary shapes were simulated using a staircase approximation, with an optimized number of steps per single slope. For the first time, an impact of dry etch processing on GaN coupler efficiency was evaluated, due to the inclusion of the sloped sidewalls, with regard to the technological constrains. Finally, the experimental results in the visible spectrum region (lambda = 633 nm), for 400-nm-deep gratings etched in GaN waveguide, were presented together with theoretical data for binary and trapezoidal profiles of a grating, for different optical mode profiles (TE(0) divided by TE(3) modes)