3 research outputs found

    Oil-Repellent Antifogging Films with Water-Enabled Functional and Structural Healing Ability

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    Healable oil-repellent antifogging films are fabricated by layer-by-layer assembly of hyaluronic acid (HA) and branched poly­(ethylenimine) (bPEI), followed by immersion in the aqueous solutions of perfluorooctanesulfonic acid potassium salt (PFOS). The loading of PFOS endows the HA/bPEI films with oil repellency while maintaining its original hydrophilicity. The resulting films have an excellent antifogging ability, and various organic liquids can easily slide down the slightly tilted films (<10°) without any residue. Through water-assisted migration of PFOS and polyelectrolytes, oil-repellent antifogging films are able to repetitively and autonomously recover their damaged oil repellency and transparency caused by plasma etching, cutting, or scratching, prolonging their life span. The as-developed healable oil-repellent antifogging films have potential application as antifingerprint coatings for touch screens, antigraffiti coatings for signs and shop windows, and antifogging coatings for lenses, mirrors, and windshields

    Durable, Highly Electrically Conductive Cotton Fabrics with Healable Superamphiphobicity

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    Electrically conductive fabrics with liquid repellency and corrosive resistance are strongly desirable for wearable displays, biomedical sensors, and so forth. In the present work, highly electrically conductive and healable superamphiphobic cotton fabrics are fabricated by a solution-dipping method that involves (NH<sub>4</sub>)<sub>2</sub>PdCl<sub>4</sub>-catalyzed electroless deposition of Cu and the subsequent deposition of a mixture of fluorinated-decyl polyhedral oligomeric silsesquioxane (F-POSS) and 1<i>H</i>,1<i>H</i>,2<i>H</i>,2<i>H</i>-perfluorooctyltriethoxysilane (POTS) on cotton fabrics. Because of their superamphiphobicity, the resulting fabrics are self-cleaning and exhibit excellent resistance against corrosive acidic and basic solutions. The as-prepared fabrics have a sheet resistance of ∼0.33 Ω·sq<sup>–1</sup> and show excellent electromagnetic interference shielding and electrothermal heating ability. Because of the preserved F-POSS and POTS molecules, the fabrics can conveniently and repeatedly restore the loss of superamphiphobicity by applying a low voltage of 1.0 V or heating the fabrics at 135 °C to facilitate the migration of the preserved F-POSS and POTS to the surface of cotton fabrics. The integration of healable superamphiphobicity into the Cu-coated fabrics generates multiple functional cotton fabrics with excellent conductivity, electromagnetic interference shielding, self-cleaning ability, and significantly enhanced durability

    Transparent Polymeric Films Capable of Healing Millimeter-Scale Cuts

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    Transparent polymeric films have been successfully integrated with self-healing capabilities. However, these films can only heal damages in the scale of several to several tens of micrometers, thereby greatly limiting their practical applications. The present study reports the fabrication of transparent polymeric films capable of healing millimeter-scale cuts by incorporating hydrogen-bonding units into zwitterionic polymer films, which are cross-linked by electrostatic interactions. The intermolecular interactions in the resulting films are greatly reduced when the films absorb water as a result of the reversibility of hydrogen-bonding and electrostatic interactions, thereby promoting the flowability of the film materials. Thus, the transparent films can heal 7.9 mm wide cuts and recover their damaged transparency following exposure to water. Furthermore, owing to their strong binding affinity to water molecules, the healable transparent films can effectively clean up oil fouled on dry films following rinsing with water. The combination of hydrogen bonding and electrostatic interactions provides a new means of design for transparent films with enhanced healing capabilities and an extended service life
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