8,574 research outputs found

    Recycling and the Environment: a Comparative Review Between Mineral-based Plastics and Bioplastics

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    Since their conception in the 1950s, mineral-based plastics have completely revolutionised our society with production reaching record highs year upon year. This cheap, and durable material has seen usage across a plethora of diverse industries and products, replacing traditional materials such as metals and wood. However, our reliance on mineral-based plastics has led to their improper disposal across the global, affecting our environments and ecosystems. As a response, different methods have been developed to help dispose of the large amounts of plastic waste produced, such as incineration or dumping in landfill sites, but these methods are not without their drawbacks including release of toxic substances into the air and leachate into the soil and waters respectively. Consequently, much interest is generated and channelled in recent years to the introduction of several types of biopolymers. These include plastics based on cellulosic esters, starch derivatives, polyhydroxybutyrate and polylactic acid. These biopolymers have been viewed as a suitable replacement for mineral-based plastics, and their production a good strategy towards sustainable development as they are mainly composed of biocompounds such as starch, cellulose and sugars. This short review article provides an overview as to whether biopolymers can rival mineral-based plastics considering properties such as mechanical strength, Young’s modulus and crystallinity and could they be regarded as a suitable material to reduce our reliance on mineral-based plastics, whilst simultaneously reducing non-renewable energy consumption and carbon dioxide emissions

    Air pollution and livestock production

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    The air in a livestock farming environment contains high concentrations of dust particles and gaseous pollutants. The total inhalable dust can enter the nose and mouth during normal breathing and the thoracic dust can reach into the lungs. However, it is the respirable dust particles that can penetrate further into the gas-exchange region, making it the most hazardous dust component. Prolonged exposure to high concentrations of dust particles can lead to respiratory health issues for both livestock and farming staff. Ammonia, an example of a gaseous pollutant, is derived from the decomposition of nitrous compounds. Increased exposure to ammonia may also have an effect on the health of humans and livestock. There are a number of technologies available to ensure exposure to these pollutants is minimised. Through proactive means, (the optimal design and management of livestock buildings) air quality can be improved to reduce the likelihood of risks associated with sub-optimal air quality. Once air problems have taken hold, other reduction methods need to be applied utilising a more reactive approach. A key requirement for the control of concentration and exposure of airborne pollutants to an acceptable level is to be able to conduct real-time measurements of these pollutants. This paper provides a review of airborne pollution including methods to both measure and control the concentration of pollutants in livestock buildings

    Plastics and Environment: Is There a Happy Medium?

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    In 2013 alone, 56 million tons of Poly(ethylene terephthalate) (PET) was produced worldwide. It’s low cost of production, coupled with desirable properties such as high durability and plasticity has led to its extensive use in many different applications, from mobile phones to medical equipment to clothing. Demand for PET is steadily increasing year by year. However, PET is mineral-based and is a non-degradable material due to its synthetic nature. It accumulates within the environment globally, and this has led to collective global efforts for developing strategies to tackle the issue using various different options. Biopolymers such as Polyhydroxyalkanoate (PHA) present themselves as a possible solution and as suitable alternative to help manage the ever-rising global demand for plastics as well as alleviating the global environmental crisis arising from non-degradable plastics. Capable to be produced in an eco-friendly manner and possessing biodegradable properties, biopolymers should be set to replace non-degradable plastics, but despite extensive research on production of biodegradable plastics, the cost of their production is too high to lend them to large-scale production. This project focuses on economic production of PHAs. In this context, several approaches are adopted. Cheaper media such as orange peel, wheat bran, and spirulina with other quality enhancing ingredients have been tried; dual polymer production has been proved a possible option, and stage-wise fermentations, appart from fed-batch have been tried. Furthermore, downstream processing strategies such as planned time of harvest have the potential to attenuate adverse effects of extraction methods for PHA extraction. A holistic approach promises positive future for biopolymer industry

    Quantitative Analysis of DoS Attacks and Client Puzzles in IoT Systems

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    Denial of Service (DoS) attacks constitute a major security threat to today's Internet. This challenge is especially pertinent to the Internet of Things (IoT) as devices have less computing power, memory and security mechanisms to mitigate DoS attacks. This paper presents a model that mimics the unique characteristics of a network of IoT devices, including components of the system implementing `Crypto Puzzles' - a DoS mitigation technique. We created an imitation of a DoS attack on the system, and conducted a quantitative analysis to simulate the impact such an attack may potentially exert upon the system, assessing the trade off between security and throughput in the IoT system. We model this through stochastic model checking in PRISM and provide evidence that supports this as a valuable method to compare the efficiency of different implementations of IoT systems, exemplified by a case study

    Origin and stability of the dipolar response in a family of tetragonal tungsten bronze relaxors

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    A new family of relaxor dielectrics with the tetragonal tungsten bronze structure (nominal composition Ba6M3+Nb9O30, M3+ = Ga, Sc or In) were studied using dielectric spectroscopy to probe the dynamic dipole response and correlate this with the crystal structure as determined from powder neutron diffraction. Independent analyses of real and imaginary parts of the complex dielectric function were used to determine characteristic temperature parameters, TVF, and TUDR, respectively. In each composition both these temperatures correlated with the temperature of maximum crystallographic strain, Tc/a determined from diffraction data. The overall behaviour is consistent with dipole freezing and the data indicate that the dipole stability increases with increasing M3+ cation size as a result of increased tetragonality of the unit cell. Crystallographic data suggests that these materials are uniaxial relaxors with the dipole moment predominantly restricted to the B1 cation site in the structure. Possible origins of the relaxor behaviour are discussed.Comment: Main article 32 pages, 8 figures; Supplementary data 24 pages, 4 figure
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