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The effect of asymmetry of the coil block on self-assembly in ABC coil-rod-coil triblock copolymers
Using the self-consistent field approach, the effect of asymmetry of the coil
block on the microphase separation is focused in ABC coil-rod-coil triblock
copolymers. For different fractions of the rod block , some stable
structures are observed, i.e., lamellae, cylinders, gyroid, and core-shell
hexagonal lattice, and the phase diagrams are constructed. The calculated
results show that the effect of the coil block fraction is
dependent on . When , the effect of asymmetry of
the coil block is similar to that of the ABC flexible triblock copolymers; When
, the self-assembly of ABC coil-rod-coil triblock copolymers
behaves like rod-coil diblock copolymers under some condition. When continues to increase, the effect of asymmetry of the coil block reduces.
For , under the symmetrical and rather asymmetrical
conditions, an increase in the interaction parameter between different
components leads to different transitions between cylinders and lamellae. The
results indicate some remarkable effect of the chain architecture on
self-assembly, and can provide the guidance for the design and synthesis of
copolymer materials.Comment: 9 pages, 3 figure
Constraints on the Inner Cluster Mass Profile and the Power Spectrum Normalization from Strong Lensing Statistics
Strong gravitational lensing is a useful probe of both the intrinsic
properties of the lenses and the cosmological parameters of the universe. The
large number of model parameters and small sample of observed lens systems,
however, have made it difficult to obtain useful constraints on more than a few
parameters from lensing statistics. Here we examine how the recent WMAP
measurements help improve the constraining power of statistics from the radio
lensing survey JVAS/CLASS. We find that the absence of theta>3'' lenses in
CLASS places an upper bound of beta<1.25 (1.60) at 68% (95%) CL on the inner
density profile, rho \propto r^{-beta}, of cluster-sized halos. Furthermore,
the favored power spectrum normalization is sigma_8 >= 0.7 (95% CL). We discuss
two possibilities for stronger future constraints: a positive detection of at
least one large-separation system, and next-generation radio surveys such as
LOFAR.Comment: Scatter in concentration included; virial mass used consistently; new
Fig 3. Final version published in ApJ
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A Body-Nonlinear Green's Function Method with Viscous Dissipation Effects for Large-Amplitude Roll of Floating Bodies
A novel time-domain body-nonlinear Green’s function method is developed for evaluating large-amplitude roll damping of two-dimensional floating bodies with consideration of viscous dissipation effects. In the method, the instantaneous wetted surface of floating bodies is accurately considered, and the viscous dissipation effects are taken into account based on the “fairly perfect fluid” model. As compared to the method based on the existing inviscid body-nonlinear Green’s function, the newly proposed method can give a more accurate damping coefficient of floating bodies rolling on the free surface with large amplitudes according to the numerical tests and comparison with experimental data for a few cases related to ship hull sections with bilge keels
Effect of polymer concentration and length of hydrophobic end block on the unimer-micelle transition broadness in amphiphilic ABA symmetric triblock copolymer solutions
The effects of the length of each hydrophobic end block N_{st} and polymer
concentration \bar{\phi}_{P} on the transition broadness in amphiphilic ABA
symmetric triblock copolymer solutions are studied using the self-consistent
field lattice model. When the system is cooled, micelles are observed, i.e.,the
homogenous solution (unimer)-micelle transition occurs. When N_{st} is
increased, at fixed \bar{\phi}_{P}, micelles occur at higher temperature, and
the temperature-dependent range of micellar aggregation and half-width of
specific heat peak for unimer-micelle transition increase monotonously.
Compared with associative polymers, it is found that the magnitude of the
transition broadness is determined by the ratio of hydrophobic to hydrophilic
blocks, instead of chain length. When \bar{\phi}_{P} is decreased, given a
large N_{st}, the temperature-dependent range of micellar aggregation and
half-width of specific heat peak initially decease, and then remain nearly
constant. It is shown that the transition broadness is concerned with the
changes of the relative magnitudes of the eductions of nonstickers and solvents
from micellar cores.Comment: 8 pages, 4 figure
Argon protects against hypoxic-ischemic brain injury in neonatal rats through activation of Nuclear factor (erythroid-derived 2)-like 2
Perinatal hypoxic ischaemic encephalopathy (HIE) has a high mortality rate with neuropsychological impairment. This study investigated the neuroprotective effects of argon against neonatal hypoxic-ischaemic brain injury. In vitro cortical neuronal cell cultures derived from rat foetuses were subjected to an oxygen and glucose deprivation (OGD) challenge for 90 minutes and then exposed to 70% argon or nitrogen with 5% carbon dioxide and balanced with oxygen for 2 hours. In vivo, seven-day-old rats were subjected to unilateral common carotid artery ligation followed by hypoxic (8% oxygen balanced with nitrogen) insult for 90 minutes. They were exposed to 70% argon or nitrogen balanced with oxygen for 2 hours. In vitro, argon treatment of cortical neuronal cultures resulted in a significant increase of p-mTOR and Nuclear factor (erythroid-derived 2)-like 2(Nrf2) and protection against OGD challenge. Inhibition of m-TOR through Rapamycin or Nrf2 through siRNA abolished argon-mediated cyto-protection. In vivo, argon exposure significantly enhanced Nrf2 and its down-stream effector NAD(P)H Dehydrogenase, Quinone 1(NQO1) and superoxide dismutase 1(SOD1). Oxidative stress, neuroinflammation and neuronal cell death were significantly decreased and brain infarction was markedly reduced. Blocking PI-3K through wortmannin or ERK1/2 through U0126 attenuated argon-mediated neuroprotection. These data provide a new molecular mechanism for the potential application of Argon as a neuroprotectant in HIE
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