Molecular Line Profile Fitting with Analytic Radiative Transfer Models

We present a study of analytic models of starless cores whose line profiles have ``infall asymmetry,'' or blue-skewed shapes indicative of contracting motions. We compare the ability of two types of analytical radiative transfer models to reproduce the line profiles and infall speeds of centrally condensed starless cores whose infall speeds are spatially constant and range between 0 and 0.2 km s-1. The model line profiles of HCO+ (J=1-0) and HCO+ (J=3-2) are produced by a self-consistent Monte Carlo radiative transfer code. The analytic models assume that the excitation temperature in the front of the cloud is either constant (``two-layer'' model) or increases inward as a linear function of optical depth (``hill'' model). Each analytic model is matched to the line profile by rapid least-squares fitting. The blue-asymmetric line profiles with two peaks, or with a blue shifted peak and a red shifted shoulder, can be well fit by the ``HILL5'' model (a five parameter version of the hill model), with an RMS error of 0.02 km s-1. A peak signal to noise ratio of at least 30 in the molecular line observations is required for performing these analytic radiative transfer fits to the line profiles.Comment: 48 pages, 20 figures, accepted for publication in Ap

Pair Correlations, Short Range Order and Dispersive Excitations in the Quasi-Kagome Quantum Magnet Volborthite

We present spatial and dynamic information on the s=1/2 distorted kagome antiferromagnet volborthite, Cu3V2O7(OD)2.2D2O, obtained by polarized and inelastic neutron scattering. The instantaneous structure factor, S(Q), is dominated by nearest neighbor pair correlations, with short range order at wave vectors Q1=0.65(3) {\AA}^-1 and Q2=1.15(5) {\AA}^-1 emerging below 5 K. The excitation spectrum, S(Q,{\omega}), reveals two steep branches dispersing from Q1 and Q2, and a flat mode at {\omega}=5.0(2) meV. The results allow us to identify the cross-over at T*=1 K in 51V NMR and specific heat measurements as the build-up of correlations at Q_1. We compare our data to theoretical models proposed for volborthite, and demonstrate that the excitation spectrum can be explained by spin-wave-like excitations with anisotropic exchange parameters, as also suggested by recent local density calculations.Comment: Rewritten article resubmitted to Phys. Rev. Lett. 021

Dust absorption and scattering in the silicon K-edge

The composition and properties of interstellar silicate dust are not well understood. In X-rays, interstellar dust can be studied in detail by making use of the fine structure features in the Si K-edge. The features in the Si K-edge offer a range of possibilities to study silicon-bearing dust, such as investigating the crystallinity, abundance, and the chemical composition along a given line of sight. We present newly acquired laboratory measurements of the silicon K-edge of several silicate-compounds that complement our measurements from our earlier pilot study. The resulting dust extinction profiles serve as templates for the interstellar extinction that we observe. The extinction profiles were used to model the interstellar dust in the dense environments of the Galaxy. The laboratory measurements, taken at the Soleil synchrotron facility in Paris, were adapted for astrophysical data analysis and implemented in the SPEX spectral fitting program. The models were used to fit the spectra of nine low-mass X-ray binaries located in the Galactic center neighborhood in order to determine the dust properties along those lines of sight. Most lines of sight can be fit well by amorphous olivine. We also established upper limits on the amount of crystalline material that the modeling allows. We obtained values of the total silicon abundance, silicon dust abundance, and depletion along each of the sightlines. We find a possible gradient of $0.06\pm0.02$ dex/kpc for the total silicon abundance versus the Galactocentric distance. We do not find a relation between the depletion and the extinction along the line of sight.Comment: 18 pages, 16 figures. Accepted for publication in Astronomy and Astrophysic

Direct and Regioselective Di-alpha-fucosylation on the Secondary Rim of beta-Cyclodextrin

A straightforward glycosylation method is described to regio- and stereoselectively introduce two alpha-L-fucose moieties directly to the secondary rim of beta-cyclodextrin. Using NMR and MS fragmentation studies, the nonasaccharide structure was determined, which was also visualized using molecular dynamics simulations. The reported glycosylation method proved to be robust on gram-scale, and may be generally applied to directly glycosylate beta-cyclodextrins to make well-defined multivalent glycoclusters.</p

GPS radio sources: new optical observations and an updated master list

* Aims. Identify optical counterparts, address uncertain identifications and measure previously unknown redshifts of the host galaxies of candidate GPS radio sources, and study their stellar populations. * Methods. Long slit spectroscopy and deep optical imaging in the B, V and R bands, obtained with the Very Large Telescope. * Results. We obtain new redshifts for B0316+161, B0407-658, B0904+039, B1433-040, and identify the optical counterparts of B0008-421 and B0742+103. We confirm the previous identification for B0316+161, B0407-658, B0554-026, and B0904+039, and find that the previous identification for B0914+114 is incorrect. Using updated published radio spectral information we classify as non GPS the following sources: B0407-658, B0437-454, B1648+015. The optical colors of typical GPS sources are consistent with single instantaneous burst stellar population models but do not yield useful information on age or metallicity. A new master list of GPS sources is presented.Comment: 10 pages + GPS master list. Accepeted for publication by A&

Scaling of spontaneous rotation with temperature and plasma current in tokamaks

Using theoretical arguments, a simple scaling law for the size of the intrinsic rotation observed in tokamaks in the absence of momentum injection is found: the velocity generated in the core of a tokamak must be proportional to the ion temperature difference in the core divided by the plasma current, independent of the size of the device. The constant of proportionality is of the order of $10\,\mathrm{km \cdot s^{-1} \cdot MA \cdot keV^{-1}}$. When the intrinsic rotation profile is hollow, i.e. it is counter-current in the core of the tokamak and co-current in the edge, the scaling law presented in this Letter fits the data remarkably well for several tokamaks of vastly different size and heated by different mechanisms.Comment: 5 pages, 3 figure

The problematically short superwind of OH/IR stars - Probing the outflow with the 69 {\mu}m spectral band of forsterite

Spectra of OH/IR stars show prominent spectral bands of crystalline olivine (Mg$_{(2-2x)}$Fe$_{(2x)}$SiO$_{4}$). To learn more about the timescale of the outflows of OH/IR stars, we study the spectral band of crystalline olivine at 69 {\mu}m. The 69 {\mu}m band is of interest because its width and peak wavelength position are sensitive to the grain temperature and to the exact composition of the crystalline olivine. With Herschel/PACS, we observed the 69 {\mu}m band in the outflow of 14 OH/IR stars. By comparing the crystalline olivine features of our sample with those of model spectra, we determined the size of the outflow and its crystalline olivine abundance. The temperature indicated by the observed 69 {\mu}m bands can only be reproduced by models with a geometrically compact superwind ($R_{\rm{SW}}\lesssim$ 2500 AU = 1400 R$_{*}$).This means that the superwind started less than 1200 years ago (assuming an outflow velocity of 10 km/s). The small amount of mass lost in one superwind and the high progenitor mass of the OH/IR stars introduce a mass loss and thus evolutionary problem for these objects, which has not yet been understood.Comment: Accepted by A&