Dynamical Behaviors of Rumor Spreading Model with Control Measures

Rumor has no basis in fact and flies around. And in general, it is propagated for a certain motivation, either for business, economy, or pleasure. It is found that the web does expose us to more rumor and increase the speed of the rumors spread. Corresponding to these new ways of spreading, the government should carry out some measures, such as issuing message by media, punishing the principal spreader, and enhancing management of the internet. In order to assess these measures, dynamical models without and with control measures are established. Firstly, for two models, equilibria and the basic reproduction number of models are discussed. More importantly, numerical simulation is implemented to assess control measures of rumor spread between individuals-to-individuals and medium-to-individuals. Finally, it is found that the amount of message released by government has the greatest influence on the rumor spread. The reliability of government and the cognizance ability of the public are more important. Besides that, monitoring the internet to prevent the spread of rumor is more important than deleting messages in media which already existed. Moreover, when the minority of people are punished, the control effect is obvious

Nickelâ Catalyzed Crossâ Coupling of (Hetero)aryl Chlorides with Aryllithium Compounds

The nickel pincer complexes [Ni(Cl){N(2â R2PC6H4)(2â ²â Me2NC6H4)}] (R=Ph, 1â a; R=iPr, 1â b; R=Cy, 1â c) were demonstrated to catalyze crossâ coupling of aryl or heteroaryl chlorides with aryllithium compounds under mild reaction conditions. The catalytic activity of 1â a was highest and resulted in biaryl products in 23â 96â % yields. A series of aryl chlorides including deactivated ones, such as 1â chloroâ 4â methoxybenzene, 4â chloroâ N,Nâ dimethylaniline, and 1â chloroâ 4â methylbenzene, and heteroaryl chlorides, including 2â and 3â chloropyridine, 2â chloroâ 4â methylquinoline, 2â chlorothiophene, 2â chlorobenzofuran, 2â chlorobenzo[d]oxazole, and 2â chlorobenzo[d]thiazole, were used in this coupling reaction.Nick and pin: The crossâ coupling of aryl or heteroaryl chlorides with aryllithium compounds catalyzed by nickel pincer complexes was performed under mild reaction conditions to afford biaryls in 23â 96â % yields.Peer Reviewedhttps://deepblue.lib.umich.edu/bitstream/2027.42/137480/1/ajoc201600045_am.pdfhttps://deepblue.lib.umich.edu/bitstream/2027.42/137480/2/ajoc201600045.pdfhttps://deepblue.lib.umich.edu/bitstream/2027.42/137480/3/ajoc201600045-sup-0001-misc_information.pd

Interlayer Interactions in Anisotropic Atomically-thin Rhenium Diselenide

Recently, two-dimensional (2D) materials with strong in-plane anisotropic properties such as black phosphorus have demonstrated great potential for developing new devices that can take advantage of its reduced lattice symmetry with potential applications in electronics, optoelectronics and thermoelectrics. However, the selection of 2D material with strong in-plane anisotropy has so far been very limited and only sporadic studies have been devoted to transition metal dichalcogenides (TMDC) materials with reduced lattice symmetry, which is yet to convey the full picture of their optical and phonon properties, and the anisotropy in their interlayer interactions. Here, we study the anisotropic interlayer interactions in an important TMDC 2D material with reduced in-plane symmetry - atomically thin rhenium diselenide (ReSe2) - by investigating its ultralow frequency interlayer phonon vibration modes, the layer dependent optical bandgap, and the anisotropic photoluminescence (PL) spectra for the first time. The ultralow frequency interlayer Raman spectra combined with the first study of polarization-resolved high frequency Raman spectra in mono- and bi-layer ReSe2 allows deterministic identification of its layer number and crystal orientation. PL measurements show anisotropic optical emission intensity with bandgap increasing from 1.26 eV in the bulk to 1.32 eV in monolayer, consistent with the theoretical results based on first-principle calculations. The study of the layer-number dependence of the Raman modes and the PL spectra reveals the relatively weak van der Waals interaction and 2D quantum confinement in atomically-thin ReSe2.Comment: 17 pages, 5 figures, supplementary informatio

MESH : a flexible manifold-embedded semantic hashing for cross-modal retrieval

Hashing based methods for cross-modal retrieval has been widely explored in recent years. However, most of them mainly focus on the preservation of neighborhood relationship and label consistency, while ignore the proximity of neighbors and proximity of classes, which degrades the discrimination of hash codes. And most of them learn hash codes and hashing functions simultaneously, which limits the flexibility of algorithms. To address these issues, in this article, we propose a two-step cross-modal retrieval method named Manifold-Embedded Semantic Hashing (MESH). It exploits Local Linear Embedding to model the neighborhood proximity and uses class semantic embeddings to consider the proximity of classes. By so doing, MESH can not only extract the manifold structure in different modalities, but also can embed the class semantic information into hash codes to further improve the discrimination of learned hash codes. Moreover, the two-step scheme makes MESH flexible to various hashing functions. Extensive experimental results on three datasets show that MESH is superior to 10 state-of-the-art cross-modal hashing methods. Moreover, MESH also demonstrates superiority on deep features compared with the deep cross-modal hashing method. © 2013 IEEE

2-Amino-4-(2-chloro­phen­yl)-7,7-di­methyl-5-oxo-5,6,7,8-tetra­hydro-4H-chromene-3-carbonitrile hemihydrate

The asymmetric unit of the title compound, C18H17ClN2O2·0.5H2O, contains two organic mol­ecules and one solvent water mol­ecule. In each organic mol­ecule, the cyclo­hexene ring adopts an envelope conformation with the C atom connecting the two methyl groups on the flap; the 4H-pyran ring is nearly planar [maximum deviation = 0.113 (3) Å in one mol­ecule and 0.089 (3) Å in the other mol­ecule] and is approximately perpendicular to the chloro­phenyl ring [dihedral angle = 86.43 (15)° in one mol­ecule and 89.73 (15)° in the other mol­ecule]. Inter­molecular N—H⋯N, N—H⋯O, O—H⋯O and O—H⋯Cl hydrogen bonding is present in the crystal

L-carnitine ameliorated fatty liver in high-calorie diet/STZ-induced type 2 diabetic mice by improving mitochondrial function

<p>Abstract</p> <p>Background</p> <p>There are an increasing number of patients suffering from fatty liver caused by type 2 diabetes. We intended to study the preventive and therapeutic effect of L-carnitine (LC) on nonalcoholic fatty liver disease (NAFLD) in streptozotocin (STZ)-induced type 2 diabetic mice and to explore its possible mechanism.</p> <p>Methods</p> <p>Thirty male Kungming mice were randomly divided into five groups: control group, diabetic group, pre-treatment group (125 mg/kg BW), low-dose (125 mg/kg BW) therapeutic group and high-dose (250 mg/kg BW) therapeutic group. The morphology of hepatocytes was observed by light and electron microscopy. LC and ALC (acetyl L-carnitine) concentrations in the liver were determined by high-performance liquid chromatography (HPLC). Moreover, liver weight, insulin levels and free fatty acid (FFA) and triglyceride (TG) levels in the liver and plasma were measured.</p> <p>Results</p> <p>Average liver LC and ALC levels were 33.7% and 20% lower, respectively, in diabetic mice compared to control mice (P < 0.05). After preventive and therapeutic treatment with LC, less hepatocyte steatosis, clearer crista and fewer glycogen granules in the mitochondria were observed. Decreased liver weight, TG levels, and FFA concentrations (P < 0.05) in the liver were also observed after treatment with LC in diabetic mice. Moreover, liver LC and ALC levels increased upon treatment with LC, whereas the ratio of LC and ALC decreased significantly (P < 0.01).</p> <p>Conclusion</p> <p>LC supplements ameliorated fatty liver in type 2 diabetic mice by increasing fatty acid oxidation and decreasing the LC/ALC ratio in the liver. Therefore, oral administration of LC protected mitochondrial function in liver.</p