5-(Pyridin-4-yl)isophthalic acid

In the title compound, C13H9NO4, the two carb­oxy­lic groups and the benzene ring are approximately co-planar with a maximum atomic deviation 0.175 (4) Å, while the pyridine ring is oriented at a dihedral angle of 31.07 (18)° with respect to the benzene ring. In the crystal, mol­ecules are linked by O—H⋯O, O—H⋯N and weak C—H⋯O hydrogen bonds, forming a three-dimensional supra­molecular framework

Experimental research on evolving rules of segregation ice in artificial frozen soil

AbstractThe foundation of frost heave controlling is the research on evolving rules of segregation ice. The evolving rules of segregation ice have been researched systematically by one-dimension freezing experiments. The technique of dynamic photograph has been applied in research for the first time. The research on segregation ice indicated that three phases can be divided according to the change of temperature field: few segregation ices appeared in the first phases, several thin and discontinuous segregation ices appeared in the second phases, segregation ice evolvement was mainly the growth of final ice lens in the third phase when the freezing front tended to be stable

Observing the Redshifted 21 cm Signal around a Bright QSO at z ∼ 10

We use hydrodynamics and radiative transfer simulations to study the 21 cm signal around a bright QSO at z ~ 10. Due to its powerful UV and X-ray radiation, the QSO quickly increases the extent of the fully ionized bubble produced by the pre-existing stellar type sources, in addition to partially ionizing and heating the surrounding gas. As expected, a longer QSO lifetime, t QSO, results in a 21 cm signal in emission located at increasingly larger angular radii, θ, and covering a wider range of θ. Similar features can be obtained with a higher galactic emissivity efficiency, f UV, such that determining the origin of a large ionized bubble (i.e., QSO versus stars) is not straightforward. Such degeneracy could be reduced by taking advantage of the finite light travel time effect, which is expected to affect an H ii region produced by a QSO differently from one created by stellar type sources. From an observational point of view, we find that the 21 cm signal around a QSO at various QSO could be detected by Square Kilometre Array1-low instrument with a high signal-to-noise ratio (S/N). As a reference, for t QSO = 10 Myr, a S/N ~ 8 is expected assuming that no pre-heating of the intergalactic medium has taken place due to high-z energetic sources, while it can reach values above 10 in cases of pre-heating. Observations of the 21 cm signal from the environment of a high-z bright QSO could then be used to set constraints on its lifetime, as well as to reduce the degeneracy between f UV and t QSO

Graphene Field-Effect Transistor for Terahertz Modulation

The real-world applications of terahertz (THz) technology necessitate versatile adaptive optical components, for example, modulators. In this chapter, we begin with a brief review on different techniques for THz modulation. After that, we introduce the extraordinary features of graphene along with its advantages and disadvantages as channel materials for field effect transistor (FET). We then discuss two types of graphene FET-based THz modulators, one is rigid and another is flexible. The feasibility of the high-quality THz modulators with different graphene FET structures has been successfully demonstrated. It is observed that by tuning the carrier concentration of graphene by electrical gating, the THz modulation can be obtained with relatively large modulation depth, broad width band, and moderate speed. This chapter helps the reader in obtaining guidelines for the proper choice of a specific structure for THz modulator with graphene FET