High-Performance Nanocatalyst for Adsorptive and Photo-Assisted Fenton-Like Degradation of Phenol: Modeling Using Artificial Neural Networks

<p>High-performance activated carbon-zinc oxide (Ac–ZnO) nanocatalyst was fabricated via the microwave-assisted technique. Ac–ZnO was characterized and the results indicated that Ac–ZnO is stable, had a band gap of 3.26 eV and a surface area of 603.5 m²g⁻¹, and exhibited excellent adsorptive and degrading potentials. About 93% phenol was adsorbed within 550 min of reaction by Ac–ZnO. Impressively, a complete degradation was achieved in 90 min via a photo-Fenton/Ac–ZnO system under optimum conditions. An artificial neural network (ANN) model was developed and applied to study the relative significance of input variables affecting the degradation of phenol in a photo-Fenton process. The ANN results indicate that increases in both H₂O₂ and Ac–ZnO dosage enhanced the rate of phenol degradation. The highest rate constant at the optimum conditions was 0.093 min⁻¹ and it was found to be consistent with the ANN-predicted rate constant (0.095 min⁻¹).</p