catena-Poly[[[aqua­[2-(6-chloro­pyridin-3-yl)acetato-κO]sodium]-di-μ-aqua] monohydrate]

The crystal structure of the title compound, {[Na(C7H5ClNO2)(H2O)3]·H2O}n, features polymeric chains along [010]. The Na+ cation is octa­hedrally coordinated by four bridging water mol­ecules, a terminal water mol­ecule and an O atom derived from a monodentate carboxyl­ate ligand. Adjacent polyhedra share two O⋯O edges. The polymeric chains are linked into a three-dimensional network via O—H⋯O and O—H⋯N hydrogen bonds

Properties of Hydrogel-Wood Composite as a New Thermochromic Glazing Material

Recently, thermal-response hydrogel smart window is widely studied because of its high luminous transmittance (τlum) and high solar modulation ability (Δτsol). However, its liquid state is undesirable for window applications. Wood has strong mechanical strength and low thermal conductivity. Due to the unique features of the thermal-response hydrogel and wood, a thermochromic hydrogel wood composite (HWC) that can smartly regulate solar irradiation is proposed by impregnating a thermal-response hydrogel into delignified wood. The novel HWC demonstrates advanced optical properties (i.e. τlum = 83% and 40% at the cold transparent and hot opaque states & Δτsol = 38%) and low transition temperature (i.e. Tc = 23 oC). Moreover, the HWC is highly flexible and easily fitted into existing windows frames. Overall, the HWC with its impressive features shows great promise for energy-efficient material for smart windows in buildings.publishedVersio

Technical research on the emission performance of vehicles with different Technique route under real driving conditions

Based on a large number of test data obtained from real driving emission test of gasoline vehicles, the emission performance of vehicles with different technique route under real driving conditions were studied, the emission sensitivities and feasible schemes to meet the China 6 RDE standards for vehicles with different technologies were also evaluated. It is revealed that for the tested fleet covering different emission control technologies and under current proposed RDE limit, the passing rate can reach 72% at the initial implementation stage of China 6 standard, and increased to more than 85% after more than one year of China 6 standard implementation, the main failure cause were the over standard emission of PN; the RDE pollution control level of domestic brands is equivalent to that of the foreign brands, but there is a certain gap between WLTC pollution control level; adding GPF is a relatively safe technology to deal with PN emission both in on road RDE tests and laboratory WLTC tests, and vehicles with additional coated GPF can obtain relatively better NOx emission performance

Optimization of ship speed and fleet deployment under carbon emissions policies for container shipping

In this paper, under the consideration of two carbon emissions policies, the issues of optimizing ship speed and fleet deployment for container shipping were addressed. A mixed-integer nonlinear programming model of ship speed and fleet deployment was established with the objective of minimising total weekly operating costs. A simulated annealing algorithm was proposed to solve the problem. An empirical analysis was conducted with the data selected from the benchmark suite. The applicability and effectiveness of the established model and its algorithm are verified by the results. According to the results, two policies of the cap-and-trade programme and the carbon tax can better optimize the results of the ship speed and fleet deployment problem to achieve the goal of reducing carbon emissions. The research remarks in this paper will provide a solution for container shipping companies to make optimized decisions under carbon emissions policies

A Location-Allocation Model for Seaport-Dry Port System Optimization

Seaports participate in hinterland economic development through partnerships with dry ports, and the combined seaport-dry port network serves as the backbone of regional logistics. This paper constructs a location-allocation model for the regional seaport-dry port network optimization problem and develops a greedy algorithm and a genetic algorithm to obtain its solution. This model is applicable to situations under which the geographic distribution of demand is known. A case study involving configuration of dry ports near the west bank of the Taiwan Strait is conducted, and the model is successfully applied

Complete genome sequencing and comparative genomic analysis of three donkey Streptococcus equi subsp. equi isolates

IntroductionStreptococcus equi subspecies equi (S. equi) is the causative agent of strangles, which is one of the most common and highly contagious respiratory infectious illnesses in horses. Streptococcus equi (S. equi) is a horse-specific pathogen that originated from the closely related zoonotic pathogen Streptococcus equi subspecies zooepidemicus (S. zooepidemicus). Despite decades of research, the movement of genetic material across host-restricted diseases remains a mystery.MethodsThree S. equi donkey isolates (HTP133, HTP232, and HT1112) were recently isolated from a strangles epidemic on donkey farms in China’s Xinjiang Province. In this study, we performed a comprehensive comparative analysis of these isolates using whole genome sequencing and compared them to the published genomic sequences of equine strain S. equi 4047 to uncover evidence of genetic events that shaped the evolution of these donkey S. equi isolates’ genomes.ResultsWhole genome sequencing indicated that both strains were closely related, with comparable gene compositions and a high rate of shared core genomes (1788-2004). Our comparative genomic study indicated that the genome structure is substantially conserved across three donkey strains; however, there are several rearrangements and inversions when compared to the horse isolate S. equi 4047. The virulence factors conveyed by genomic islands and prophages, in particular, played a key role in shaping the pathogenic capacity and genetic diversity of these S. equi strains. Furthermore, we discovered that the HT133 isolate had a strong colonization ability and increased motility; the HT1112 isolates had a significantly higher ability for antimicrobial resistance and biofilm formation, and the HT232 isolate gained pathogenic specialization by acquiring a bacteriophage encoding hyaluronate lyase.DiscussionIn summary, our findings show that genetic exchange across S. equi strains influences the development of the donkey S. equi genome, offering important genetic insights for future epidemiological studies of S. equi infection