6 research outputs found
Multifunctional characterization of carbon nanotube sheets, yarns, and their composites
Carbon nanotube (CNT) based macroscopic objects such as dry-state free-standing sheets and yarns have attracted much attention during more than a decade for their multifunctional features. Thanks to their lightweight, highly conductive, mechanically strong and flexible properties, various applications had been explored so far. However, because of the difficulties in the spinnable CNT forest growth, the sample availability in the academic fields has been quite limited. In this report, various properties of CNT sheets, yarns, and their composites were experimentally presented using the samples prepared from the spinnable CNT forest grown in the newly installed, acetylene-based, chemical-vapor-deposition chamber system. Clear observation of the dimensional effect on the charge transport through CNTs, the enhancement of electro-mechanical actuation owing the volume-expandable infiltration material inside CNTs, and other exemplary evaluations proved the versatility of this macroscopic assembly as well as the good quality of our sample. Ā© 2016 Elsevier B.V.1681sciescopuskc
Ferroelectric Single-Crystal Gated Graphene/Hexagonal-BN/Ferroelectric Field-Effect Transistor
The effect of a ferroelectric polarization field on the charge transport in a two-dimensional (2D) material was examined using a graphene monolayer on a hexagonal boron nitride (hBN) field-effect transistor (FET) fabricated using a ferroelectric single-crystal substrate, (1-x)[Pb(Mg1/3Nb2/3)O3]-x[PbTiO3] (PMN-PT). In this configuration, the intrinsic properties of graphene were preserved with the use of an hBN flake, and the influence of the polarization field from PMN-PT could be distinguished. During a wide-range gate-voltage (VG) sweep, a sharp inversion of the spontaneous polarization affected the graphene channel conductance asymmetrically as well as an antihysteretic behavior. Additionally, a transition from antihysteresis to normal ferroelectric hysteresis occurred, depending on the VG sweep range relative to the ferroelectric coercive field. We developed a model to interpret the complex coupling among antihysteresis, current saturation, and sudden conductance variation in relation with the ferroelectric switching and the polarization-assisted charge trapping, which can be generalized to explain the combination of 2D structured materials with ferroelectrics. Ā© 2015 American Chemical Society125211sciescopu
Carbon-Nanotube-Templated, Sputter-Deposited, Flexible Superconducting NbN Nanowire Yarns
Flexible superconducting yarns consisting of sputter-deposited NbN nanowires on highly aligned carbon nanotube (CNT) array sheets are reported. In the microscopic view, the NbN nanowires are formed on top of individual CNT fibrils, and the superconductivity property of the twist-spun NbN-CNT yarn system is comparable to that of a typical NbN thin film on a normal solid substrate. Because of its intrinsic porosity, the system exhibits superior mechanical flexibility with a small bending radius. It also remains a superconducting state even when subjected to severe mechanical deformations, primarily due to the proximity superconductivity through carbon nanotube bundles. The results demonstrate the possibility of fabricating flexible superconducting yarns in a conventional thin-film deposition process, using ultraflexible free-standing CNT sheets as a template. In addition, preliminary tests on reducing the normal-state resistance toward superconducting cable applications are presented. Ā© 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim1111sciescopu
Highly twisted supercoils for superelastic multi-functional fibres
The development of electrically conductive fibres is attractive for wearable electronics, but performance should be maintained upon deformation and tensile strain. Here the authors fabricate flexible, stretchable, carbon nanotube-coated spandex fibres for supercapacitors and artificial muscles
Ultrastretchable Analog/Digital Signal Transmission Line with Carbon Nanotube Sheets
Stretchable
conductors can be used in various applications depending on their
own characteristics. Here, we demonstrate simple and robust elastomeric
conductors that are optimized for stretchable electrical signal transmission
line. They can withstand strains up to 600% without any substantial
change in their resistance (ā¤10% as is and ā¤1% with
passivation), and exhibit suppressed charge fluctuations in the medium.
The inherent elasticity of a polymeric rubber and the high conductivity
of flexible, highly oriented carbon nanotube sheets were combined
synergistically, without losing both properties. The nanoscopic strong
adhesion between aligned carbon nanotube arrays and strained elastomeric
polymers induces conductive wavy folds with microscopic bending of
radii on the scale of a few micrometers. Such features enable practical
applications such as in elastomeric length-changeable electrical digital
and analog signal transmission lines at above MHz frequencies. In
addition to reporting basic direct current, alternating current, and
noise characterizations of the elastomeric conductors, various examples
as a stretchable signal transmission line up to 600% strains are presented
by confirming the capability of transmitting audio and video signals,
as well as low-frequency medical signals without information distortion
Ultrastretchable Analog/Digital Signal Transmission Line with Carbon Nanotube Sheets
Stretchable
conductors can be used in various applications depending on their
own characteristics. Here, we demonstrate simple and robust elastomeric
conductors that are optimized for stretchable electrical signal transmission
line. They can withstand strains up to 600% without any substantial
change in their resistance (ā¤10% as is and ā¤1% with
passivation), and exhibit suppressed charge fluctuations in the medium.
The inherent elasticity of a polymeric rubber and the high conductivity
of flexible, highly oriented carbon nanotube sheets were combined
synergistically, without losing both properties. The nanoscopic strong
adhesion between aligned carbon nanotube arrays and strained elastomeric
polymers induces conductive wavy folds with microscopic bending of
radii on the scale of a few micrometers. Such features enable practical
applications such as in elastomeric length-changeable electrical digital
and analog signal transmission lines at above MHz frequencies. In
addition to reporting basic direct current, alternating current, and
noise characterizations of the elastomeric conductors, various examples
as a stretchable signal transmission line up to 600% strains are presented
by confirming the capability of transmitting audio and video signals,
as well as low-frequency medical signals without information distortion