Influences of Combined Organic Fouling and Inorganic Scaling on Flux and Fouling Behaviors in Forward Osmosis

This study investigated the influence of combined organic fouling and inorganic scaling on the flux and fouling behaviors of thin-film composite (TFC) forward osmosis (FO) membranes. Two organic macromolecules, namely, bovine serum albumin (BSA) and sodium alginate (SA), and gypsum (GS), as an inorganic scaling agent, were selected as model foulants. It was found that GS scaling alone caused the most severe flux decline. When a mixture of organic and inorganic foulants was employed, the flux decline was retarded, compared with when the filtration was performed with only the inorganic scaling agent (GS). The early onset of the conditioning layer formation, which was due to the organics, was probably the underlying mechanism for this inhibitory phenomenon, which had suppressed the deposition and growth of the GS crystals. Although the combined fouling resulted in less flux decline, compared with GS scaling alone, the concoction of SA and GS resulted in more fouling and flux decline, compared with the mixture of BSA and GS. This was because of the carboxyl acidity of the alginate, which attracted calcium ions and formed an intermolecular bridge

A short review of membrane fouling in forward osmosis processes

Interest in forward osmosis (FO) research has rapidly increased in the last decade due to problems of water and energy scarcity. FO processes have been used in many applications, including wastewater reclamation, desalination, energy production, fertigation, and food and pharmaceutical processing. However, the inherent disadvantages of FO, such as lower permeate water flux compared to pressure driven membrane processes, concentration polarisation (CP), reverse salt diffusion, the energy consumption of draw solution recovery and issues of membrane fouling have restricted its industrial applications. This paper focuses on the fouling phenomena of FO processes in different areas, including organic, inorganic and biological categories, for better understanding of this long-standing issue in membrane processes. Furthermore, membrane fouling monitoring and mitigation strategies are reviewed.Published versio

Pre-deposited dynamic membrane filtration - a review

A dynamic membrane (DM) is a layer of particles deposited via permeation drag onto a conventional membrane, such that the deposited particles act as a secondary membrane that minimizes fouling of the primary membrane to lower transmembrane pressures (TMP) and enable higher permeate fluxes. Since the first DM was created in 1966 at the Oak Ridge National Laboratory, numerous studies have reported synthesis of DMs using various materials and explored their abilities to perform reverse osmosis (RO), nanofiltration (NF), ultrafiltration (UF) and microfiltration (MF). DMs are classified into two categories, namely, (i) self-formed, whereby the feed constituents form the DM; and (ii) pre-deposited, whereby the DM is formed by a layer of particles other than the feed prior to introduction of the feed. This paper endeavors to present a comprehensive review of the state-of-the-art on the latter. Key materials used as DMs, their formation and various factors influencing it, regeneration of DMs and modifications to DM systems for performance enhancement are discussed. The role of DMs in preventing fouling in the primary membrane (PM) is explained. The applications of DMs in four major areas, namely, salt and organic solute rejection, treatment of industrial effluents, treatment of water and wastewater, and oily-wastewater treatment are reviewed. Furthermore, technical and economic advantages of DMs over conventional processes are considered, and challenges in current DM research are discussed. Finally, directions for future research are suggested.National Research Foundation (NRF)Public Utilities Board (PUB)This research grant was supported by the Singapore National Research Foundation under its Environment and Water Research Program and administered by PUB, Singapore’s National Water Agency (grant number: 1601-CRPW-T20). The Singapore Membrane Technology Center, Nanyang Environment and Water Research Institute, Nanyang Technological University is supported by the Economic Development Board of Singapore

Forward osmosis as a pre-treatment for treating coal seam gas associated water: Flux and fouling behaviours

In this study, a bench scale forward osmosis (FO) process was operated using two commonly available FO membranes in different orientations in order to examine the removal of foulants in the coal seam gas (CSG) associated water, the water flux and fouling behaviours of the process were also investigated. After 48 h of fouling simulation experiment, the water flux declined by approximately 55 and 35% of its initial level in the TFC-PRO and CTA-PRO modes (support layer facing the feed), respectively, while the flux decline in the TFC-FO and CTA-FO modes (active layer facing the feed) was insignificant. The flux decline in PRO modes was caused by the compounding effects of internal concentration polarisation and membrane fouling. However, the declined flux was completely recovered to its initial level following the hydraulic cleaning using deionised water. Dissolved organic carbon (DOC), adenosine tri-phosphate (ATP) and major inorganic scalants (Ca, Mg and silica) in the CSG feed were effectively removed by using the FO process. The results of this study suggest that the FO process shows promising potential to be employed as an effective pre-treatment for membrane purification of CSG associated water

Prototype aquaporin-based forward osmosis membrane : filtration properties and fouling resistance

The trade-off between water permeability and selectivity is considered as the biggest challenge during membrane fabrication for water purification. The aquaporin (AQP)-based biomimetic membrane has been proven to have both enhanced water permeability and improved selectivity due to the unique features of the AQP protein water channel that permits water molecules and rejects all other components. In this study, a prototype forward osmosis (FO) Aquaporin Inside™ membrane (AIM) was evaluated in terms of intrinsic filtration properties, membrane surface chemistry and fouling behaviour, and compared with a commercial FO membrane. The surface of the prototype AIM appeared to be a modified semi-aromatic polyamide layer instead of fully-aromatic as in other conventional FO products. As a result, compared to the commercial FO membrane, the prototype AIM shows higher water flux and comparable reverse salt flux (RSF) when tested under identical conditions. Due to the lower RSF, the AIM had less organic fouling by a sodium alginate solution when calcium chloride (CaCl2) was used as the draw solution (DS). The membrane integrity of the prototype AIM was maintained after repeated cycles of fouling by high concentration of gypsum and physical cleaning tests. This demonstrates the possibility of using the AIM membrane for treating harsh feed solutions.NRF (Natl Research Foundation, S’pore)EDB (Economic Devt. Board, S’pore

Organic matter removal from a membrane bioreactor effluent for reverse osmosis fouling mitigation by microgranular adsorptive filtration system

In this study, a prototype microgranular adsorptive filtration (μGAF) system was constructed employing a 7-bore ceramic membrane as the primary membrane and either heated aluminum oxide particles (HAOPs) or powdered activated carbon (PAC) as the pre-deposited dynamic membrane (DM). The system was used to pre-treat membrane bioreactor (MBR) effluent from a full-scale MBR-reverse osmosis (RO) water reclamation plant. The downstream RO performance and membrane fouling potential of the treated effluent were then assessed. The results indicated that: (i) although PAC removed more overall EfOM than HAOPs did, HAOPs were more effective in removing biopolymers such as polysaccharides and proteins, (ii) HAOPs virtually eliminated fouling of the primary ceramic membrane, whereas considerable fouling (much of it irreversible) occurred when the feed was pretreated with PAC, (iii) HAOPs removed more than 90% of the phosphorus and fluoride from the feed, but PAC removed negligible amounts of these contaminants, and (iv) HAOPs-treated effluent resulted in only a 43% decline in RO permeate water flux over 5 d of continuous filtration, as opposed to 62% flux decline for untreated or PAC-treated effluent. This study thus demonstrates the effectiveness of the HAOPs-based μGAF process as a pre-treatment for improving downstream RO recovery.Economic Development Board (EDB)National Research Foundation (NRF)Submitted/Accepted versionThis research grant was supported by the Singapore National Research Foundation under its Environment and Water Research Program and administered by PUB, Singapore’s National Water Agency (grant number: 1601-CRPW-T20). The Singapore Membrane Technology Center, Nanyang Environment and Water Research Institute, Nanyang Technological University is supported by the Economic Development Board of Singapore